Aromatic Metallacycles: Syntheses, Structures, and Properties

芳香族金属环：合成、结构和性质

• 批准号: 0647252
• 负责人: Michael Haley
• 金额: $ 42.2万
• 依托单位: University of Oregon Eugene
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-03-01 至 2011-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0647252&HistoricalAwards=false
• 关键词: Aromatic; Metallacycles; Syntheses; Structures; Properties

This project is focused on the preparation and studies of new metalla-aromatic topologies to answer fundamental scientific questions about structure, bonding, and properties of metallacycles, as well as to explore the potential uses of these systems. In addition to the preparation of vinylcyclopropene ligands, Pt, Rh, and group VIII complexes, computational studies will also be performed. Application of metallacycles in the preparation of nonlinear optical materials and conducting polyacetylene analogs will also be studied. With this award, the Organic and Macromolecular Chemistry Program is supporting the research of Professor Michael M. Haley, of the Department of Chemistry at University of Oregon Eugene. Professor Haley's research efforts revolve around the discovery, development, and exploitation of metallacycles. Such studies will not only enhance our understanding of a new class of compounds, they may also lead to the preparation of novel nonlinear optical materials and conducting polymers.

该项目的重点是制备和研究新的金属芳香拓扑结构，以回答有关金属环的结构，键合和性质的基本科学问题，以及探索这些系统的潜在用途。 除了制备乙烯基环丙烯配体，铂，铑，和第八组配合物，计算研究也将进行。 金属杂环化合物在非线性光学材料和导电聚乙炔类似物制备中的应用也将进行研究。 有了这个奖项，有机和高分子化学计划是支持教授迈克尔M。俄勒冈州大学尤金化学系的哈利说。 哈利教授的研究工作围绕着金属环的发现、开发和利用。 这些研究不仅将增强我们对一类新化合物的理解，还可能导致制备新型非线性光学材料和导电聚合物。