Exploratory Investigation of Thermally-Induced Water Flow in Soils

土壤中热诱导水流的探索性研究

• 批准号: 1562522
• 负责人: Zhen Liu
• 金额: $ 9.68万
• 依托单位: Michigan Technological University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-05-01 至 2018-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1562522&HistoricalAwards=false
• 关键词: Exploratory; Investigation; Thermally; Induced; Water

This project aims to answer a very fundamental yet very old scientific question: "Why and how does water move due to temperature gradients in porous materials?" This thermally induced water flux ubiquitously exists in porous materials, whenever both heat transfer and water movement are present. A scientific understanding of this phenomenon is an essential base for many important scientific and social challenges: climate effects on geomaterials, geothermal energy applications, behavior of porous materials under extreme conditions, and recovery of non-conventional fossil fuels such as gas hydrates and shale gas. However, despite the significance, this phenomenon has been an historically unsolved and perplexing issue affecting many science and engineering areas involving porous materials from traditional applications in civil engineering, soil science and petroleum engineering to emerging needs in microfluidics, material processing and biomechanics. This award supports the exploration of a new research concept/methodology and its application to reveal the physical mechanisms underlying thermally induced water flux for a complete scientific description and analysis framework for this phenomenon. As an exploratory study, which pioneers a very high-risk but possibly high-return concept, the success of the study may provide the geotechnical community a new understanding to tackle many issues which are hard to solve in the existing frameworks, and also provide a way to integrate porous material research which is currently distributed in various disciplines. In addition to supporting a doctoral student, the project will support outreach activities for rural, low-socioeconomic students and native tribal communities in the Upper Peninsula of Michigan. An annual summer program will be established to engage K-12 students in hands-on-learning for understanding of porous materials.This project will utilize a new concept/methodology, multiscale-driven multiphysics, to tackle the issue which appears difficult to solve with existing methods. The research will first focus on the macroscopic mechanisms underlying thermally induced water flux. For the purpose, thermally induced water flux will be related to the temperature dependence of the contact angle by conducting two sub-tasks: 1. measuring thermally induced water flux with a newly designed research setup, and 2. measuring the contact angle using a modified capillary rise method. Then molecular dynamics analysis will be carried out to reveal the microscopic mechanisms underneath the temperature dependence of the contact angle, which is hypothesized to be attributable to the temperature dependence of vapor adsorption. Finally, adsorption isotherms will be measured to experimentally validate the hypotheses and to couple the frameworks at both macro- and micro-scales, aiming at a physically-based and practically implementable framework for thermally induced water flux. The research is potentially very important as it attempts at breakthroughs via innovations on the theoretical (new theories at both macro and micro-scale), experimental (contact angle and thermally induced flux measurements), and numerical aspects (molecular simulations for water-mineral system). In the long term, the project also serves as an exploratory effort to examine the concept of multiscale-driven multiphysics, for the purpose of enabling solutions to critical historical issues and pressing challenges arising from upcoming applications in sustainability, energy and environmental protection, which more and more involve non-isothermal behavior of soils, and in a broad sense, multiphysics in porous materials.

该项目旨在回答一个非常基本但又非常古老的科学问题：“为什么以及如何由于多孔材料中的温度梯度而使水移动？“这种热致水通量普遍存在于多孔材料中，无论何时都存在传热和水运动。对这一现象的科学理解是许多重要科学和社会挑战的重要基础：气候对地质材料的影响，地热能应用，极端条件下多孔材料的行为，以及天然气水合物和页岩气等非常规化石燃料的回收。然而，尽管意义重大，这一现象一直是一个历史上未解决的和令人困惑的问题，影响到许多科学和工程领域，涉及多孔材料从传统的应用在土木工程，土壤科学和石油工程的新兴需求，在微流体，材料加工和生物力学。该奖项支持探索新的研究概念/方法及其应用，以揭示热致水通量的物理机制，为这一现象提供完整的科学描述和分析框架。作为一项探索性研究，它开创了一个非常高风险但可能高回报的概念，该研究的成功可能会为岩土界提供一个新的认识，以解决现有框架中难以解决的许多问题，并提供一种方法来整合目前分布在各个学科的多孔材料研究。 除了支持一名博士生外，该项目还将支持为密歇根州上半岛的农村、低社会经济地位的学生和土著部落社区开展的外联活动。每年的暑期项目将建立一个让K-12学生动手学习的项目，以了解多孔材料。该项目将利用一个新的概念/方法，多尺度驱动的多物理场，来解决现有方法难以解决的问题。研究将首先集中在热诱导水通量的宏观机制。为此，热诱导水通量将通过进行两个子任务与接触角的温度依赖性相关：1.用新设计的研究装置测量热致水通量，以及2.使用改进的毛细管上升法测量接触角。然后进行分子动力学分析，以揭示接触角的温度依赖性下的微观机制，这是假设可归因于蒸汽吸附的温度依赖性。最后，将测量吸附等温线，以实验验证的假设，并耦合在宏观和微观尺度的框架，旨在在物理为基础的和实际可实施的框架热诱导水通量。该研究可能非常重要，因为它试图通过理论创新（宏观和微观尺度的新理论），实验（接触角和热诱导通量测量）和数值方面（水-矿物系统的分子模拟）取得突破。 从长远来看，该项目还作为一种探索性的努力，以研究多尺度驱动的多物理场的概念，目的是解决关键的历史问题和即将到来的可持续性，能源和环境保护应用所带来的紧迫挑战，这些应用越来越多地涉及土壤的非等温行为，从广义上讲，多孔材料中的多物理场。