Investigation of Extreme Near-Field Thermal Radiation at Sub-10-nm Vacuum Gap Distances

CBET -1605584 PI：Park，Keunhan当物体之间的差距小于热辐射的波长时，辐射热传递的速率可以显著超过预期速率。 这一观察使创新的技术应用，如近场热光伏发电，热整流和局部辐射冷却。 该项目的目标是近场热辐射的实验验证，这是相对未开发的，特别是对于小于10纳米的间隙。这项研究的结果将提供知识的光谱分布的热辐射能量及其传输在极端近场制度。 该项目的结果将引发纳米级中红外光的检测，成像和光谱学以及近场热光伏发电机的发展。 该项目将通过本科生和研究生参与拟议的研究活动，促进培训和学习。此外，K-12推广将通过犹他州科学奥林匹克，工程日和犹他州纳米日进行。极端近场热辐射的实验和理论研究将完成：（1）测量极端近场辐射热传输加热针尖和表面之间的超真空原子力显微镜（UHV-AFM）;（2）通过尖端增强的光电流产生和尖端散射的热辐射测量近场热谱;以及（3）通过数值精确和近似方法模拟尖端-表面近场热相互作用。该项目的创新功能源于在定制的UHV-AFM中使用尖端平面配置，该配置与反射光学器件连接，允许测量尖端散射的热辐射以及直接的尖端-衬底热和辐射相互作用。自制的电阻式纳米温度计和定制的光伏中红外探测器将被实现为直接测量尖端-衬底近场能量传输的衬底。将获得的实验数据与称为热离散偶极子近似的数值模型进行比较，以了解影响极端近场热辐射和辐射到传导转变的潜在机制和因素。这项研究将提供定量测量的极端近场热辐射，这将允许，在串联的理论模型，波动电动力学的基础上的连续理论的适用性的限制的确定。此外，近场热辐射的广泛光谱分析将揭示了解近场效应的热辐射光谱，包括潜在的光谱红移时，尖端是在近场与基板的相互作用。本文的理论工作将克服目前基于点偶极子的尖-面近场热辐射模型的挑战。

CBET - 1605584PI: Park, KeunhanThe rate of radiative heat transfer can significantly exceed the expected rate when the gap between objects is smaller than the wavelength of the thermal radiation. This observation enables innovative technological applications such as near-field thermophotovoltaic power generation, thermal rectification and local radiative cooling. The objective of this project is the experimental validation of near-field thermal radiation, which is relatively unexplored, especially for gaps less than 10 nanometers. The outcome of this research will provide knowledge in the spectral distribution of thermal radiative energy and its transport in the extreme near-field regime. Results of the project will spark the development of detection, imaging and spectroscopy of mid-infrared light at the nanoscale as well as near-field thermophotovoltaic power generators. The project will promote training and learning through the involvement of undergraduate and graduate students in the proposed research activities. Additionally, K-12 outreach will be performed via the Utah Science Olympiad, Engineering Day and Utah Nano Days.Experimental and theoretical investigation of extreme near-field thermal radiation will be accomplished by: (1) measuring the extreme near-field radiative heat transport between a heated tip and a surface in an ultrahigh vacuum atomic force microscope (UHV-AFM); (2) measuring the near-field thermal spectrum via tip-enhanced photocurrent generation and tip-scattered thermal radiation; and (3) modeling tip-surface near-field thermal interactions via numerically exact and approximate methods. Innovative features of this project originate from using the tip-plane configuration in a customized UHV-AFM, which is interfaced with reflective optics that allows the measurement of tip-scattered thermal radiation in conjunction with direct tip-substrate thermal and radiative interactions. Home-built resistive nanothermometers and a customized photovoltaic mid-infrared detector will be implemented as a substrate to directly measure tip-substrate near-field energy transport. The obtained experimental data will be compared against the numerical model, called the thermal discrete dipole approximation, to understand the underlying mechanisms and factors affecting extreme near-field thermal radiation and radiation-to-conduction transition. This research will provide quantitative measurements of extreme near-field thermal radiation which will allow, in tandem with the theoretical models, the determination of the limit of applicability of the continuum theory based on fluctuational electrodynamics. In addition, an extensive spectroscopic analysis of near-field thermal radiation will shed light on understanding the near-field effects on the thermal radiation spectrum, including the potential spectral redshift when a tip is in near-field interactions with a substrate. The proposed theoretical work will overcome the challenge of the current point-dipole based tip-plane near-field thermal radiation model.