In Operando Characterization of Degradation Processes in Organic Semiconductor Materials

有机半导体材料降解过程的现场表征

• 批准号: 1608289
• 负责人: Jeanne Pemberton
• 金额: $ 59万
• 依托单位: University of Arizona
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-07-01 至 2020-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1608289&HistoricalAwards=false
• 关键词: Operando; Characterization; Degradation; Processes; Organic

Non-technical AbstractOrganic semiconductor materials hold exceptional promise in a number of existing and emerging technologies including optoelectronics, thermoelectrics, bioelectronics, and energy harvesting and storage applications. Degradation of these materials during use is a major issue in the commercial implementation of organic semiconductors. These degradation pathways are thought to be a complex combination of effects resulting from exposure to small amounts of gases and moisture in the ambient atmosphere as well as ultraviolet radiation. With the support of the Solid State and Materials Chemistry program, this foundational effort allows development of sophisticated, state-of-the-art spectroscopic tools based on the interaction of light and electrons with these materials to identify the chemical pathways that accompany degradation, leading to better solutions to solve this complicated problem. This inherently interdisciplinary effort has substantial broader impact through the professional development of the graduate students involved. Graduate students conduct a portion of their dissertation research in the laboratory of the other Principal Investigator, as well as complete a 6-week internship at Next Energy Technologies, Inc. Technical AbstractSolid-state organic semiconductor materials are the essential active components of a variety of existing and emerging technologies, including light-emitting diode lasers and organic-based electronic and photonic devices. These technologies suffer from limited lifetimes due to the inevitable degradation of organic semiconductors through poorly defined chemical, photochemical and photophysical processes, especially in operando, or under conditions of operation. Addressing these limitations requires characterization of the molecular structural, electronic, and charge transport attributes of these organic semiconductor materials during and after degradation. Toward this end, a suite of state-of-the-art methods, including surface vibrational spectroscopies (Raman, PM-IRRAS) in ambient to ultrahigh vacuum, x-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), inverse photoemission spectroscopy (IPES), and charge mobility measurements, are used to study organic semiconductors in environments that systematically increase in chemical and optoelectronic complexity, including in operando. The primary objective of this effort is to undertake a comprehensive fundamental investigation of the chemical, photochemical, and photophysical mechanisms of degradation that underlie the diminished performance and eventual failure of organic semiconductor-based devices. The secondary impact of this effort is formulation of new design criteria for more robust organic semiconductors.

有机半导体材料在许多现有和新兴技术中具有特殊的前景，包括光电子学、热电学、生物电子学以及能量收集和存储应用。这些材料在使用过程中的降解是有机半导体商业应用中的主要问题。这些降解途径被认为是暴露于环境大气中的少量气体和水分以及紫外线辐射所产生的影响的复杂组合。在固态和材料化学计划的支持下，这一基础工作允许开发基于光和电子与这些材料相互作用的复杂的最先进的光谱工具，以确定伴随降解的化学途径，从而更好地解决这个复杂的问题。这种内在的跨学科努力通过所涉及的研究生的专业发展产生了广泛的影响。研究生在其他主要研究者的实验室进行部分论文研究，并在Next Energy Technologies，Inc.完成为期6周的实习。固态有机半导体材料是各种现有和新兴技术的基本活性组分，包括发光二极管激光器和有机基电子和光子器件。这些技术由于有机半导体通过不明确的化学、光化学和光物理过程（特别是在操作中或在操作条件下）不可避免地降解而具有有限的寿命。解决这些限制需要表征这些有机半导体材料在降解期间和之后的分子结构、电子和电荷传输属性。为此，一套最先进的方法，包括表面振动光谱，（拉曼，PM-IRRAS）、X射线光电子能谱（XPS）、紫外光电子能谱（UPS）、逆光电子能谱（IPES）和电荷迁移率测量，用于研究在化学和光电复杂性系统地增加的环境中的有机半导体，包括歌剧这项工作的主要目标是进行一个全面的基本调查的化学，光化学和生物物理降解机制的基础上的性能下降，并最终失败的有机电催化剂为基础的设备。这一努力的第二个影响是制定了更坚固的有机半导体的新设计标准。