OP: Nonlinear Optical Properties of Organic Cavity Polaritons

非技术性描述：光与能够吸收和发射光的物质的相互作用具有根本和长期的科学和技术兴趣。这种相互作用可以通过使用由两个镜子组成的微型光学腔来增强，其中光在穿过吸收介质时反复来回反射。这种结构构成了激光器的基础。通常用于制造激光器的有机染料，当放置在超小的光学腔中时，表现出特别增强的行为，通常以异常大的颜色变化为例。该项目解决了小于光波长的光学腔中的非线性光学效应，其中上述增强特别强。 与表现出这些异常强的相互作用的特殊光学材料耦合的光学腔可以被动态地控制，并且因此，这些系统的光学性能。本计画所探讨的现象在光资讯处理与通讯，以及全息显示等技术上有潜在的应用。参与这个项目的研究生和本科生也参与了对来自俄亥俄州东北部内城代表性不足群体的学生的指导和外展计划。技术描述：最近在室温下观测到了含有有机染料和半导体的微腔中光子和激子之间的超强耦合。 异常强的相互作用与相同材料的鲁棒非线性光学响应相吻合。这为光子学提供了一种新的和有前途的杂化材料。本计画探讨有机材料作为奈米级低Q光学腔中主动元件之非线性光学性质，并探讨腔极化激元之强与超强光子-激子耦合机制。在这种情况下，量子腔电动力学的物理学描述了复合结构的光谱色散的显着变化。对AC斯塔克效应的贡献是研究的焦点，这意味着特别注意非线性光学相互作用的光谱响应和通过改变腔共振（例如，通过角度调谐）来操纵光谱。本文从实验和理论两方面研究了有机玻璃作为非线性光学材料的低Q金属镜腔结构，以确定它们对光学克尔效应、三次谐波产生和光折变的非线性光学响应。

Nontechnical description: The interaction of light with matter capable of light absorption and emission is of fundamental and long-standing scientific and technological interest. This interaction can be enhanced by using miniature optical cavities made of two mirrors, in which light repeatedly bounces back and forth while traversing the absorbing medium. This structure forms the basis of the laser. Organic dyes, commonly used for making lasers, exhibit particularly enhanced behavior when placed in ultrasmall optical cavities, often exemplified by unusually large color changes. This project addresses nonlinear optical effects in optical cavities smaller than the wavelength of light, in which the aforementioned enhancements are particularly strong. The optical cavities coupled with the special optical materials exhibiting these exceptionally strong interactions can be dynamically controlled, and, as a result, the optical performance of these systems. The phenomena addressed in this project have potential applications in optical information processing and communications, and in such technologies as holographic displays. The graduate and undergraduate students involved in this project are also involved in mentoring and outreach programs for students from underrepresented groups in the inner cities in northeast Ohio.Technical description: Ultrastrong coupling between photons and excitons in microcavities containing organic dyes and semiconductors has been recently observed at room temperature. The unusually strong interactions dovetail with the robust nonlinear optical responses of the same materials. This provides a new and promising hybrid material for photonics. This project explores the nonlinear optical properties of organic materials as active elements in nanoscale low-Q optical cavities in the regime of strong and ultrastrong photon-exciton coupling of cavity polaritons. In this regime, the physics of quantum cavity electrodynamics describes significant changes in the spectral dispersion of the composite structure. Contributions to the AC Stark effect is the focus of studies implying particular attention to spectral response of the nonlinear optical interaction and manipulation of the spectrum by varying the cavity resonance, for example, by angle tuning. Well-studied organic glass forming nonlinear optical materials incorporated into metal mirror cavities of low-Q are being investigated, experimentally and theoretically, in a number of cavity configurations to determine their nonlinear optical response for the optical Kerr effect, third harmonic generation and photorefraction.