RII Track-4: Pore-Scale Transport Phenomena in Li-O2 Battery Electrodes Characterized by Nano-Tomography

RII Track-4：通过纳米断层扫描表征锂氧电池电极中的孔隙尺度传输现象

• 批准号: 1833048
• 负责人: Xianglin Li
• 金额: $ 21.93万
• 依托单位: University of Kansas Center for Research Inc
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-10-01 至 2022-09-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1833048&HistoricalAwards=false
• 关键词: RII; Track; Pore; Scale; Transport

Nontechnical DescriptionRechargeable batteries with high specific energy and power are the key for high-performance and long-range electric vehicles as well as many portable power applications. The lithium-oxygen (Li-O2) battery has great potential as the next generation energy storage technology. However, the current achievable specific energy (i.e., energy per unit mass) for Li-O2 batteries is a factor of ten lower than its theoretical limit and their current power performance are still far below the acceleration performance required for electric vehicles. Both of these limitations are partially due to the sluggish mass transfer of oxygen in the electrode. Increasing the specific energy requires fundamental knowledge of pore-scale material transport in battery electrodes. To fill this knowledge gap, the PI will work with collaborators at Carnegie Mellon University (CMU) to measure and reconstruct the pore-scale structure of Li-O2 battery electrodes and propose criteria for fundamentally improving the electrochemical performance of Li-O2 batteries. Research findings from this Fellowship will also be integrated into curriculum development efforts to transmit the new theory and knowledge to young researchers, train undergraduate and graduate students, and nurture a skilled and educated professional workforce to grow local industry and economy.Technical DescriptionThe collaboration with Prof. Shawn Litster and access to the unique X-ray Computed Tomography Facility (XCFT) at CMU, made possible by this Fellowship, is the key to reconstructing high-resolution (~50 nm) pore-scale structure and for subsequent studies of Li-O2 batteries. The reconstructed three-dimensional nano-tomography of customized battery electrodes will 1) be integrated with statistical models to transfer pore-scale morphology to electrode-level properties; 2) be coupled with fluid dynamics models to predict its electrochemical performance; and 3) facilitate the understanding of pore structure evolution caused by the solid Li2O2 precipitation/depletion during discharge/charge. The new knowledge and theory, as well as the new techniques, developed in this project will enable research and development of advanced electrode materials to significantly improve the specific energy and power of Li-O2 batteries. The profound scientific significance will last beyond this Fellowship and promote electrochemical technologies with high energy and power density such as fuel cells, Li-ion batteries, metal-air batteries, super capacitors, and redox flow batteries. The success of this project will initiate a longstanding collaboration between the PI and Prof. Litster to pursue new knowledge and foster more collaborative research between the University of Kansas and CMU. It also provides an excellent opportunity for one graduate student to receive systematic training on conducting scientific research, initiating collaborations, and disseminating research findings each summer.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术性说明具有高比能量和功率的可充电电池是高性能和长距离电动汽车以及许多便携式电源应用的关键。锂氧电池作为下一代储能技术具有巨大的潜力。然而，目前可实现的比能量（即，每单位质量的能量）比其理论极限低十倍，并且它们当前的功率性能仍然远低于电动车辆所需的加速性能。这两个限制部分地是由于电极中氧气的缓慢传质。提高比能量需要电池电极中孔隙尺度材料传输的基础知识。为了填补这一知识空白，PI将与卡内基梅隆大学（CMU）的合作者合作，测量和重建Li-O2电池电极的孔尺度结构，并提出从根本上改善Li-O2电池电化学性能的标准。该奖学金的研究成果也将被纳入课程开发工作中，以向年轻研究人员传播新的理论和知识，培训本科生和研究生，并培养一批训练有素的专业劳动力，以发展当地工业和经济。技术说明与Shawn Litster教授的合作以及使用CMU独特的X射线计算机断层扫描设备（XCFT），该奖学金使之成为可能，是重建高分辨率（~50 nm）孔隙尺度结构和后续研究锂氧电池的关键。定制电池电极的重建三维纳米断层扫描将1）与统计模型集成，以将孔尺度形态转化为电极级性质; 2）与流体动力学模型耦合，以预测其电化学性能; 3）促进理解放电/充电期间固体Li 2 O2沉淀/耗尽引起的孔结构演变。该项目开发的新知识和理论以及新技术将使先进电极材料的研究和开发能够显着提高Li-O2电池的比能量和功率。其深远的科学意义将超越本奖学金，并促进具有高能量和功率密度的电化学技术，如燃料电池，锂离子电池，金属空气电池，超级电容器和氧化还原液流电池。该项目的成功将启动PI和Litster教授之间的长期合作，以追求新的知识，并促进堪萨斯大学和CMU之间的更多合作研究。该奖项还为一名研究生提供了一个很好的机会，让他们在每年夏天接受关于开展科学研究、发起合作和传播研究成果的系统培训。该奖项反映了NSF的法定使命，并通过使用基金会的智力价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Effect of solvent for tailoring the nanomorphology of multinary CuCo2S4 for overall water splitting and energy storage

• DOI: 10.1016/j.jallcom.2019.01.012
• 发表时间: 2019-05
• 期刊: Journal of Alloys and Compounds
• 影响因子: 6.2
• 作者: C. Zequine;S. Bhoyate;Fangzhou Wang;Xianglin Li;K. Siam;P. Kahol;R. Gupta

Experimental Studies of Carbon Electrodes With Various Surface Area for Li–O2 Batteries

• DOI: 10.1115/1.4043229
• 发表时间: 2019-11
• 期刊: Journal of Electrochemical Energy Conversion and Storage
• 影响因子: 2.5
• 作者: Fangzhou Wang;P. Kahol;R. Gupta;Xianglin Li

Needle grass array of nanostructured nickel cobalt sulfide electrode for clean energy generation

• DOI: 10.1016/j.surfcoat.2018.09.045
• 发表时间: 2018-11
• 期刊: Surface and Coatings Technology
• 影响因子: 5.4
• 作者: C. Zequine;S. Bhoyate;K. Siam;P. Kahol;Nikolaos Kostoglou;C. Mitterer;S. Hinder;M. Baker;G. Constantinides;C. Rebholz;Gautam Gupta;Xianglin Li;R. Gupta

Efficient reconstruction and validation of heterogeneous microstructures for energy applications

• DOI: 10.1002/er.8578
• 发表时间: 2022-09
• 期刊: International Journal of Energy Research
• 影响因子: 4.6
• 作者: Andre Adam;Fangzhou Wang;Xianglin Li

Nanosheets of CuCo2O4 As a High-Performance Electrocatalyst in Urea Oxidation

• DOI: 10.3390/app9040793
• 发表时间: 2019-02-02
• 期刊: APPLIED SCIENCES-BASEL
• 影响因子: 2.7
• 作者: Zequine, Camila;Wang, Fangzhou;Gupta, Ram K.
• 通讯作者: Gupta, Ram K.