Collaborative Research: Tunable Control of Mixed Ionic and Electronic Conductivity through Ion Irradiation in Electroceramic Materials for Energy Storage System

合作研究：通过离子辐照可调谐控制储能系统电陶瓷材料中的混合离子和电子电导率

• 批准号: 1838604
• 负责人: Hui Xiong
• 金额: $ 31.96万
• 依托单位: Boise State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-04-01 至 2024-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1838604&HistoricalAwards=false
• 关键词: Collaborative; Research; Tunable; Control; Mixed

NON-TECHNICAL DESCRIPTION: The goal of this foundational study is to significantly improve the performance of lithium ion batteries. These batteries are among the most promising energy storage technologies and are much needed for near-term growth of the renewable energy and electric vehicle markets. This project examines how electroceramic materials (used in batteries) can be intentionally altered by adding impurities or producing other defects. For electrode (i.e., anode and cathode) materials, conductivity is critical for high energy and high-power lithium ion batteries. Recent research demonstrates improved performance when electrode materials contain defects, with the potential to extend battery energy, power density, stability, tolerance in extreme conditions, and calendar life. This project focuses on and explores the model oxide system, titania (TiO2) to shed light on the underlying conductivity phenomena in these electroceramic materials. In addition, this project is coupled to education, diversity, and training activities that are integrated across two participating universities (Boise State and Purdue). For example, this project is implementing a cross-institutional undergraduate researcher 'exchange' program.TECHNICAL DETAILS: This study presents a unique method for tailoring ionic/electronic conductivity using irradiation, which could open new research pathways in irradiation-enhanced materials functionality and lead to an unprecedented advancement in tailoring electrochemical performance in electroceramic materials. The project investigates the hypothesis that irradiation-induced defects can provide tunable control over the mixed ionic/electronic conductivity in electroceramic materials, thus delivering enhanced electrochemical properties for lithium-ion battery applications. Electrodes containing extrinsic (e.g., doping) and intrinsic defects (e.g., vacancies, cation disorder) exhibit improved electrochemical properties. Specifically, extrinsic defects may enhance electronic conductivity, while intrinsic defects may enhance ionic conductivity. Intermediate energy ion irradiation creates intrinsic defects, while the irradiating ion species becomes implanted in the target material as extrinsic defects. Thus, it is theorized that the appropriate selection of the irradiating ion species and energy enables tuning of the ionic and electronic conductivity to produce better electrochemical properties. This project focuses on a model metal oxide, TiO2 (anatase). Specimens irradiated with niobium ions to produce both intrinsic and extrinsic defects, are compared to specimens irradiated with helium ions, which diffuse from the target material and leave behind only intrinsic defects. The hypothesis is being tested on crystalline thin films, which enables a mechanistic understanding of intermediate energy irradiation effects on metal oxides to be formed. Building on these results, research on a polycrystalline nanoarchitectured TiO2 electrode follows to elucidate the ion irradiation effect on the electrochemical properties of the electrode. This research is being incorporated into teaching and outreach modules for integration across the two participating institutions and is being made available via NanoHUB.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术描述：这项基础性研究的目标是显著提高锂离子电池的性能。这些电池是最有前途的储能技术之一，对于可再生能源和电动汽车市场的短期增长来说是非常必要的。这个项目研究了电子陶瓷材料(用于电池)是如何通过添加杂质或产生其他缺陷来故意改变的。对于电极(即正极和负极)材料，导电性是高能、高功率锂离子电池的关键。最近的研究表明，当电极材料含有缺陷时，性能会得到改善，有可能延长电池的能量、功率密度、稳定性、极端条件下的耐受性和日历寿命。本项目重点研究和探索模型氧化物系统二氧化钛(二氧化钛)，以揭示这些电子陶瓷材料中潜在的导电现象。此外，该项目还与两所参与大学(博伊西州立大学和普渡大学)整合的教育、多样性和培训活动相结合。例如，这个项目正在实施一个跨机构的本科生研究人员交流计划。技术细节：这项研究提出了一种利用辐射来定制离子/电子导电性的独特方法，这可能在辐射增强材料功能方面开辟新的研究途径，并导致在定制电子陶瓷材料的电化学性能方面取得前所未有的进步。该项目研究的假设是，辐照诱导的缺陷可以对电子陶瓷材料中的混合离子/电子导电性进行可调控制，从而为锂离子电池应用提供更好的电化学性能。含有外在缺陷(如掺杂)和本征缺陷(如空位、阳离子无序)的电极表现出更好的电化学性质。具体地说，非本征缺陷可能会增强电子电导，而本征缺陷可能会增强离子电导。中能离子辐照产生本征缺陷，而辐照离子物种作为外在缺陷被注入靶材。因此，理论上认为，适当选择辐照离子的种类和能量可以调节离子和电子的导电性，从而产生更好的电化学性质。该项目的重点是模型金属氧化物，二氧化钛(锐钛矿型)。将用Nb离子辐照产生本征和非本征缺陷的样品与用氦离子辐照的样品进行比较，氦离子从靶材料扩散，只留下本征缺陷。这一假设正在晶体薄膜上进行测试，这使得人们能够从机理上理解中等能量辐照对金属氧化物的影响。在这些结果的基础上，对多晶纳米结构的二氧化钛电极进行了研究，以阐明离子辐照对电极电化学性质的影响。这项研究正在被纳入两个参与机构的教学和推广模块，并通过NanoHUB提供。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Effect of proton irradiation on anatase TiO2 nanotube anodes for lithium-ion batteries

• DOI: 10.1007/s10853-019-03825-w
• 发表时间: 2019-10
• 期刊: Journal of Materials Science
• 影响因子: 4.5
• 作者: Kassiopeia A. Smith;A. Savva;Keyou S. Mao;Yongqiang Wang;D. Tenne;Di Chen;Yuzi Liu;Pete Barnes

In situ ion irradiation of amorphous TiO2 nanotubes

• DOI: 10.1557/s43578-022-00516-2
• 发表时间: 2022-02
• 期刊: Journal of Materials Research
• 影响因子: 2.7
• 作者: Chao Yang;Tristan T. Olsen;Miu Lun Lau;Kassiopeia A. Smith;K. Hattar;Amrita Sen;Yaqiao Wu;Dewen Hou;B. Narayanan;Min Long;J. Wharry;H. Xiong