Imaging Ultrafast and Ultrasmall: Understanding and Manipulating Phase Transitions in Correlated Oxides Using Coherent X-Ray Diffraction

超快和超小型成像：使用相干 X 射线衍射了解和操纵相关氧化物中的相变

• 批准号: 1902652
• 负责人: Roopali Kukreja
• 金额: $ 55.39万
• 依托单位: University of California-Davis
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-05-01 至 2024-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1902652&HistoricalAwards=false
• 关键词: Imaging; Ultrafast; Ultrasmall; Understanding; Manipulating

NON-TECHNICAL DESCRIPTION: Modern-day semiconductor devices have led to important advances in diverse areas including information technology, energy, health, and education. To overcome the current plateau in performance of the existing microelectronics and enable energy-efficient high-speed operation, complex oxides have been identified as a possible alternative to semiconductors. This project explores the novel approach of utilizing optical lasers to manipulate magnetic and electronic properties of complex nickel oxides at ultrafast timescales. Research activities involve synthesis and advanced characterization of complex oxides at nanometer lengthscales and femtosecond timescales. The fundamental understanding of nanoscale and ultrafast phenomenon is expected to significantly impact the development of future generations of computing devices. Education activities includes introducing women and minority undergraduate students to opportunities at U.S. National Laboratories and collaborating with University of California Davis Mathematics Engineering Science Achievement (MESA) Schools Program to engage high school students in science, technology, engineering, and mathematics. This project will provide graduate and undergraduate students training in interdisciplinary fields at the intersection of materials science, physics, and electrical engineering. Graduates are likely to find future employment in the information technology sector. TECHNICAL DETAILS: The goal of this research project is to elucidate fundamental limits and mechanisms to tailor material properties at ultrasmall lengthscales and ultrafast timescales in correlated oxides including rare-earth nickelates such as neodymium nickelate and samarium nickelate. The project focuses on optically induced metal-insulator phase transitions in rare earth nickelate thin films by utilizing synchrotron and free electron laser based coherent X-ray techniques. Specific objectives include: (i) deciphering fundamental lengthscales and timescales associated with ultrafast behavior, (ii) understanding the influence of nanoscale morphology in optically induced phase transitions, and (iii) investigating the coupling of electronic, magnetic and structural degrees of freedom at femtosecond timescales. The scientific knowledge at the ultimate limits of the ultrafast/ultrasmall frontier in materials behavior discovered in this project will enable development of future generations of computing devices based on light-matter interactions. Education activities include the training of undergraduate and graduate students in state-of-the art deposition and characterization tools, including synchrotron radiation and free electron laser-based characterization techniques at U.S. National Laboratories.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术描述：现代半导体器件在包括信息技术、能源、健康和教育在内的各个领域都取得了重要进展。为了克服现有微电子性能的当前平台并实现节能高速操作，复合氧化物已被确定为半导体的可能替代品。该项目探索了利用光学激光在超快时间尺度上操纵复杂镍氧化物的磁性和电子性质的新方法。研究活动包括纳米尺度和飞秒尺度的复合氧化物的合成和高级表征。对纳米尺度和超快现象的基本理解预计将对未来几代计算设备的发展产生重大影响。教育活动包括向妇女和少数民族本科生介绍美国国家实验室的机会，并与加州戴维斯大学数学工程科学成就学校计划合作，让高中生参与科学、技术、工程和数学。该项目将为研究生和本科生提供材料科学，物理学和电气工程交叉领域的跨学科培训。毕业生很可能在信息技术部门找到未来的工作。技术规格：该研究项目的目标是阐明在相关氧化物中，包括稀土镍酸盐（如镍酸钕和镍酸钐），在超小长度尺度和超快时间尺度下定制材料性能的基本限制和机制。该项目的重点是利用同步加速器和自由电子激光器为基础的相干X射线技术在稀土镍酸盐薄膜中的光诱导金属-绝缘体相变。具体目标包括：（i）破译与超快行为相关的基本长度尺度和时间尺度，（ii）理解纳米级形态对光诱导相变的影响，以及（iii）研究飞秒时间尺度下电子、磁性和结构自由度的耦合。在该项目中发现的材料行为超快/超小前沿极限的科学知识将使未来几代基于光物质相互作用的计算设备的开发成为可能。教育活动包括对本科生和研究生进行最先进的沉积和表征工具的培训，包括美国国家实验室的同步辐射和基于自由电子激光的表征技术。该奖项反映了NSF的法定使命，并被认为值得通过使用基金会的知识价值和更广泛的影响审查标准进行评估来支持。

项目成果

Domain fluctuations in ferroelectric low-strain BaTiO3 thin film

铁电低应变 BaTiO3 薄膜的磁畴波动

• 发表时间: 2020
• 期刊: Physical review materials
• 影响因子: 3.4
• 作者: Li, Jianheng;Zhong, Louie;Jangid, Rahul;Meera, Fnu;Rippy, Geoffery;Ainslie, Kenneth;Kohne, Chris;Everhardt, Arnoud;Noheda, Beatriz;Zhang, Yugang
• 通讯作者: Zhang, Yugang

Discerning element and site-specific fluctuations of the charge-orbital order in Fe3O4 below the Verwey transition

• DOI: 10.1103/physrevmaterials.7.014413
• 发表时间: 2023-01-31
• 期刊: PHYSICAL REVIEW MATERIALS
• 影响因子: 3.4
• 作者: Hua，Nelson;Li，Jianheng;Shpyrko，Oleg G.
• 通讯作者: Shpyrko，Oleg G.

Understanding nanoscale structural distortions in Pb(Zr 0.2 Ti 0.8 )O 3 by utilizing X-ray nanodiffraction and clustering algorithm analysis

利用 X 射线纳米衍射和聚类算法分析了解 Pb(Zr 0.2 Ti 0.8 )O 3 中的纳米级结构畸变

• DOI: 10.1107/s1600577520013661
• 发表时间: 2021
• 期刊: Journal of Synchrotron Radiation
• 影响因子: 2.5
• 作者: Christiansen-Salameh, Joyce;Yang, Morris;Rippy, Geoffrey;Li, Jianheng;Cai, Zhonghou;Holt, Martin;Agnus, Guillaume;Maroutian, Thomas;Lecoeur, Philippe;Matzen, Sylvia
• 通讯作者: Matzen, Sylvia