Collaborative Research: Structure and Thermodynamics of Ionic Liquids at Solid Surfaces: the Return of Water

合作研究:固体表面离子液体的结构和热力学:水的返回

基本信息

项目摘要

Ionic liquids (ILs) have interesting physicochemical properties, including low volatility, high thermal stability, high CO2 solubility and selectivity, and unique solvation characteristics, making them promising candidates for applications involving CO2 capture, catalysis, and dispersion of colloidal particles. This collaborative project will combine experiments and molecular simulations aiming to understand the role of interfacial water at the interface between ILs and solid surfaces. The role of interfacial water on the electrification of solid surfaces and the structure of interfacial ILs will be investigated and its impact the CO2 adsorption at IL-solid interfaces will be studied. The proposed research aims to investigate the role of water on the interfacial structure of ILs and address the three-way coupling among surface electrification, water adsorption and ion self-assembly in the interfacial zone, which is crucial for resolving existing controversies on the effect of water on solid-IL interfaces. A multi-faceted experimental characterization (e.g., attenuated total reflectance Fourier transform infrared spectroscopy, X-ray reflectivity, and neutron reflectivity) will be integrated with computer simulations to obtain high-quality data and mechanistic insights on the effect of water on the structure of solid-IL interfaces and gas adsorption at these interfaces. This will help settle the controversies in the literature and provide guidelines for applications such as CO2 capture. To investigate how water affects the electrification of solid surfaces and the structure of interfacial ILs, mica will be used as the solid surface to test the hypotheses that water enables electrification of solid surfaces by effective dissolution of surface ions and impacts self-assembly of ILs via water-IL coupling. To investigate how water impacts the CO2 adsorption at IL-solid interfaces, silica will be used as the solid surface because of its relevance to applications including CO2 capture and catalysis. The insights gained from this project may enable the tailoring of solid-IL interfaces and gas adsorption at these interfaces by controlling the water content. In addition to training graduate students and developing new courses, the investigators plan to offer research opportunities to undergraduate students from underrepresented groups and pursue outreach activities to K12 students in collaboration with the Engineering Advancing Grade-school Education (ENGAGE) program at the University of Pittsburgh and the Center for the Enhancement of Engineering Diversity (CEED) at Virginia Tech.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
离子液体具有低挥发性、高热稳定性、高CO2溶解度和选择性以及独特的溶剂化特性,在CO2捕集、催化和胶体粒子分散等领域具有广阔的应用前景。这个合作项目将结合联合收割机实验和分子模拟,旨在了解界面水在离子液体和固体表面之间的界面的作用。研究了界面水对固体表面带电和界面离子液体结构的影响,以及它对离子液体-固体界面CO2吸附的影响。该研究旨在探讨水对离子液体界面结构的作用,并解决界面区表面带电,水吸附和离子自组装之间的三向耦合,这对于解决水对固体-离子液体界面影响的现有争议至关重要。多方面的实验表征(例如,衰减全反射傅里叶变换红外光谱、X射线反射率和中子反射率)将与计算机模拟相结合,以获得关于水对固体-离子液体界面结构和这些界面处的气体吸附的影响的高质量数据和机理见解。这将有助于解决文献中的争议,并为二氧化碳捕获等应用提供指导。为了研究水如何影响固体表面的带电和界面离子液体的结构,云母将被用作固体表面来测试假设,即水通过有效溶解表面离子来使固体表面带电,并通过水-离子液体耦合来影响离子液体的自组装。为了研究水如何影响IL-固体界面处的CO2吸附,将使用二氧化硅作为固体表面,因为其与包括CO2捕获和催化的应用相关。从该项目中获得的见解可以通过控制水含量来定制固体-IL界面和在这些界面处的气体吸附。除了培养研究生和开发新课程外,研究人员计划与匹兹堡大学的工程推进小学教育项目(ENGAGE)和工程多样性增强中心(CEED)合作,为来自代表性不足群体的本科生提供研究机会,并为K12学生开展推广活动该奖项反映了NSF的法定使命,并被认为是值得通过使用基金会的知识价值和更广泛的影响审查标准进行评估的支持。

项目成果

期刊论文数量(1)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Enabling Magnesium Anodes by Tuning the Electrode/Electrolyte Interfacial Structure
通过调整电极/电解质界面结构来实现镁阳极
  • DOI:
    10.1021/acsami.1c10446
  • 发表时间:
    2021
  • 期刊:
  • 影响因子:
    9.5
  • 作者:
    Wen, Xiaoyu;Yu, Zhou;Zhao, Yifan;Zhang, Jian;Qiao, Rui;Cheng, Lei;Ban, Chunmei;Guo, Juchen
  • 通讯作者:
    Guo, Juchen
{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

数据更新时间:{{ journalArticles.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ monograph.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ sciAawards.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ conferencePapers.updateTime }}

{{ item.title }}
  • 作者:
    {{ item.author }}

数据更新时间:{{ patent.updateTime }}

Rui Qiao其他文献

Recoiled Proton Tagged Knockout Reaction for He-8
He-8 的反冲质子标记敲除反应
  • DOI:
  • 发表时间:
    2012
  • 期刊:
  • 影响因子:
    1.7
  • 作者:
    Xinagqing Li;Jianling Lou;Jun Xiao;Qite Li;Linhui Lv;Kuoang Li;He Wang;Rui Qiao;Haibo You
  • 通讯作者:
    Haibo You
Ameco Beijing: Benefits of Performance Appraisals
Ameco 北京:绩效考核的好处
  • DOI:
  • 发表时间:
    2018
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Lin Ma;Xin Wu;Rui Qiao;Wenping Su
  • 通讯作者:
    Wenping Su
Synthesis, Crystal Structure and Properties of a New Cd(II)Complex Based on Mixed 5-Hydroxy-isophthalic Acid and1-(1H-imidazol-4-yl)-3-(4H-tetrazol-5-yl)benzene Ligands
5-羟基间苯二甲酸和1-(1H-咪唑-4-基)-3-(4H-四唑-5-基)苯混合配体的新型Cd(II)配合物的合成、晶体结构和性能
  • DOI:
  • 发表时间:
    2015
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Zhi-Yong Hu;Juan-Juan Zhu;Shui-Sheng Chen;Rui Qiao
  • 通讯作者:
    Rui Qiao
Carbon Flux with DAMPE Using Machine Learning Methods
使用机器学习方法使用 DAMPE 的碳通量
  • DOI:
    10.22323/1.444.0168
  • 发表时间:
    2023
  • 期刊:
  • 影响因子:
    0
  • 作者:
    M. Stolpovskiy;Francesco Alemanno;C. Altomare;Qi An;P. Azzarello;F. Barbato;P. Bernardini;Xiaomei Bi;I. Cagnoli;M. Cai;E. Casilli;E. Catanzani;Jin Chang;Dengyi Chen;Junling Chen;Zhan;Z. Chen;P. Coppin;M. Cui;T. Cui;Yunqiang Cui;I. De Mitri;Francesco de Palma;Adriano Di Giovanni;M. Di Santo;Qi Ding;T. Dong;Z. Dong;G. Donvito;D. Droz;Jingmin Duan;K. Duan;R. Fan;Yizhong Fan;F. Fang;K. Fang;Chang;Lei Feng;M. Fernandez Alonso;J. M. Frieden;Piergiorgio Fusco;Min Gao;F. Gargano;Essna Ghose;Ke Gong;Y. Gong;D. Guo;Jianhua Guo;Shuang Han;Yi;Guangshun Huang;Xiao Yuan Huang;Y. Huang;M. Ionica;Luyang Jiang;Weizhong Jiang;Y. Jiang;J. Kong;A. Kotenko;D. Kyratzis;S. Lei;W. Li;Wen Li;Xiang Li;X. Li;Y. Liang;Chengming Liu;Hao Liu;Jie Liu;S. Liu;Yang Liu;F. Loparco;C. Luo;Miao Ma;P. Ma;Tao Ma;Xiao Ma;G. Marsella;M. N. Mazziotta;D. Mo;X. Niu;Xu Pan;A. Parenti;W. Peng;X. Peng;C. Perrina;E. Putti;Rui Qiao;J. Rao;A. Ruina;Z. Shangguan;Weiming Shen;Z. Shen;Z. Shen;L. Silveri;Jing Song;H. Su;Meng Su;H. Sun;Zhiyu Sun;A. Surdo;X. Teng;A. Tykhonov;J. Wang;L. Wang;Shen Wang;X. Wang;Y. Wang;Ying Wang;Yuanzhu Wang;D. Wei;J. Wei;Yining Wei;Di Wu;Jian Wu;L. Wu;Sha Wu;Xin Wu;Z. Xia;E. Xu;Hailun Xu;Jing Xu;Z. Xu;Zizhong Xu;Zunlei Xu;G. Xue;Hai;P. Yang;Y. Yang;H. Yao;Yu;G. Yuan;Qiang Yuan;C. Yue;J. Zang;Shenmin Zhang;W. Zhang;Yan Zhang;Y. Zhang;Yi Zhang;Y. Zhang;Y. Zhang;Yunlong Zhang;Zhe Zhang;Z. Zhang;Cong;Hong;Xu Zhao;C. Zhou;Yanzi Zhu
  • 通讯作者:
    Yanzi Zhu
An intriguing case of regular RR and QRS alternans during idiopathic left posterior fascicle ventricular tachycardia
  • DOI:
    10.1016/j.jelectrocard.2020.07.022
  • 发表时间:
    2020-09-01
  • 期刊:
  • 影响因子:
  • 作者:
    Xian-Guan Zhu;Liang-Chuan Chen;Rui Qiao;Xue-Jun Xiang;Yuan-Xi Zheng
  • 通讯作者:
    Yuan-Xi Zheng

Rui Qiao的其他文献

{{ item.title }}
{{ item.translation_title }}
  • DOI:
    {{ item.doi }}
  • 发表时间:
    {{ item.publish_year }}
  • 期刊:
  • 影响因子:
    {{ item.factor }}
  • 作者:
    {{ item.authors }}
  • 通讯作者:
    {{ item.author }}

{{ truncateString('Rui Qiao', 18)}}的其他基金

Collaborative Research: Electrotunable and Curvature-Dependent Friction at Nanoscale Contacts Lubricated by Ionic Liquids
合作研究:离子液体润滑纳米级接触处的电可调和曲率相关摩擦
  • 批准号:
    2216256
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Precise and Dexterous Single-Particle Manipulation Using Non-uniform AC Magnetic Fields
合作研究:利用非均匀交流磁场进行精确灵巧的单粒子操纵
  • 批准号:
    1808307
  • 财政年份:
    2018
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Nanofluidics Foundation for Shale Gas Recovery
页岩气回收纳米流体基金会
  • 批准号:
    1705287
  • 财政年份:
    2017
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Kinetics of Autonomous Catalytic Nanomotors in Confined and Crowded Environments
合作研究:密闭和拥挤环境中自主催化纳米电机的动力学
  • 批准号:
    1464146
  • 财政年份:
    2014
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Deciphering Induced-Charge Electrokinetics: Multiscale Simulations and Nanoscale Flow Characterization
合作研究:解读感应电荷电动学:多尺度模拟和纳米级流动表征
  • 批准号:
    1464621
  • 财政年份:
    2014
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
GOALI/Collaborative Research: Fundamentals of Microemulsion Boiling: from Interfacial Thermodynamics to Multiphase Heat Transfer
GOALI/合作研究:微乳液沸腾的基础:从界面热力学到多相传热
  • 批准号:
    1463932
  • 财政年份:
    2014
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Non-Equilibrium Transport of Strongly Correlated Electrolytes in Nanopores: Fundamentals and Applications
纳米孔中强相关电解质的非平衡传输:基础与应用
  • 批准号:
    1461842
  • 财政年份:
    2014
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Deciphering Induced-Charge Electrokinetics: Multiscale Simulations and Nanoscale Flow Characterization
合作研究:解读感应电荷电动学:多尺度模拟和纳米级流动表征
  • 批准号:
    1336224
  • 财政年份:
    2013
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Kinetics of Autonomous Catalytic Nanomotors in Confined and Crowded Environments
合作研究:密闭和拥挤环境中自主催化纳米电机的动力学
  • 批准号:
    1303099
  • 财政年份:
    2013
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
GOALI/Collaborative Research: Fundamentals of Microemulsion Boiling: from Interfacial Thermodynamics to Multiphase Heat Transfer
GOALI/合作研究:微乳液沸腾的基础:从界面热力学到多相传热
  • 批准号:
    1336590
  • 财政年份:
    2013
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant

相似国自然基金

Research on Quantum Field Theory without a Lagrangian Description
  • 批准号:
    24ZR1403900
  • 批准年份:
    2024
  • 资助金额:
    0.0 万元
  • 项目类别:
    省市级项目
Cell Research
  • 批准号:
    31224802
  • 批准年份:
    2012
  • 资助金额:
    24.0 万元
  • 项目类别:
    专项基金项目
Cell Research
  • 批准号:
    31024804
  • 批准年份:
    2010
  • 资助金额:
    24.0 万元
  • 项目类别:
    专项基金项目
Cell Research (细胞研究)
  • 批准号:
    30824808
  • 批准年份:
    2008
  • 资助金额:
    24.0 万元
  • 项目类别:
    专项基金项目
Research on the Rapid Growth Mechanism of KDP Crystal
  • 批准号:
    10774081
  • 批准年份:
    2007
  • 资助金额:
    45.0 万元
  • 项目类别:
    面上项目

相似海外基金

Collaborative Research: The influence of incoming plate structure and fluids on arc melt generation at the Lesser Antilles subduction system
合作研究:来料板结构和流体对小安的列斯群岛俯冲系统电弧熔化产生的影响
  • 批准号:
    2316136
  • 财政年份:
    2024
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Continuing Grant
Collaborative Research: The influence of incoming plate structure and fluids on arc melt generation at the Lesser Antilles subduction system
合作研究:来料板结构和流体对小安的列斯群岛俯冲系统电弧熔化产生的影响
  • 批准号:
    2316137
  • 财政年份:
    2024
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Continuing Grant
Collaborative Research: Manipulating the Thermal Properties of Two-Dimensional Materials Through Interface Structure and Chemistry
合作研究:通过界面结构和化学控制二维材料的热性能
  • 批准号:
    2400352
  • 财政年份:
    2024
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Manipulating the Thermal Properties of Two-Dimensional Materials Through Interface Structure and Chemistry
合作研究:通过界面结构和化学控制二维材料的热性能
  • 批准号:
    2400353
  • 财政年份:
    2024
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Accurate and Structure-Preserving Numerical Schemes for Variable Temperature Phase Field Models and Efficient Solvers
合作研究:用于变温相场模型和高效求解器的精确且结构保持的数值方案
  • 批准号:
    2309547
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Assembling the foundation of modern mammal community structure in the first 7 million years after the K/Pg mass extinction
合作研究:为 K/Pg 大规模灭绝后的前 700 万年建立现代哺乳动物群落结构的基础
  • 批准号:
    2321344
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Molecular and Nanoscale Structure and Interactions of PFAS at Interfaces and Mixed Surfactant Systems
合作研究:PFAS 的分子和纳米结构以及界面和混合表面活性剂体系的相互作用
  • 批准号:
    2227128
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: Reducing Model Uncertainty by Improving Understanding of Pacific Meridional Climate Structure during Past Warm Intervals
合作研究:通过提高对过去温暖时期太平洋经向气候结构的理解来降低模型不确定性
  • 批准号:
    2303568
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Continuing Grant
Collaborative Research: Structure and function: How microenvironment facilitates antimicrobial response to environmental stress in a defensive symbiosis
合作研究:结构和功能:微环境如何促进防御性共生中的抗菌剂对环境应激的反应
  • 批准号:
    2247195
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
Collaborative Research: RUI: The challenges of living small: functional tradeoffs in the vertebral bone structure of diminutive mammals
合作研究:RUI:小型生活的挑战:小型哺乳动物椎骨结构的功能权衡
  • 批准号:
    2223964
  • 财政年份:
    2023
  • 资助金额:
    $ 22.17万
  • 项目类别:
    Standard Grant
{{ showInfoDetail.title }}

作者:{{ showInfoDetail.author }}

知道了