MRI: Acquisition of Mass Spectrometer-Coupled Thermogravimetric Analyzer System

MRI：采集质谱仪耦合热重分析仪系统

• 批准号: 1919810
• 负责人: Jeremy Feldblyum
• 金额: $ 11.84万
• 依托单位: SUNY at Albany
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-08-01 至 2022-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1919810&HistoricalAwards=false
• 关键词: MRI; Acquisition; Mass; Spectrometer; Coupled

This award is funded by the Major Research Instrumentation (MRI) and Chemical Instrumentation (CRIF) programs. Professor Jeremy Feldblyum from SUNY at Albany and colleagues John Welch, Rabi Musah, Evgeny Dikarev and Marina Petrukhina have acquired a thermal gravimetric analysis system equipped with a mass spectrometer (TGA-MS). This instrument measures the weight of a sample as it is heated. As vapors evolve, the samples are analyzed by a mass spectrometer to determine the mass and chemical composition of the vapors emitted. This data provides information on the identity of the sample itself and its composition (if a mixture). The vapors may be decomposition products providing information on the thermal stability of the sample. TGA-MS is a powerful tool in analyzing materials. The research may impact many areas, including organic and inorganic chemistry and polymer chemistry. One example involves the synthesis of materials which can be used to separate high-value organic compounds in hydrocarbon fuels which are difficult to separate by distillation. In another project, energy storage materials are being tested. The thermal decomposition of novel polymers used in photolithography is also being investigated. Instrumentation usage by local research institutions, including universities and colleges, commercial companies and government institutions (eg. the NY State Crime Laboratory) is encouraged. The instrument provides training opportunities for students at both the undergraduate and graduate levels in research and laboratory instruction. The acquisition of this thermogravimetric analyzer enhances the research and education of undergraduate and graduate students at SUNY at Albany and surrounding institutions. Heterometallic molecular precursors for the preparation of energy-related materials are under investigation. Metal-organic frameworks (MOFs) are being tested for separating high-value organic compounds. Storage materials such as for hydrogen capture are being synthesized and tested. The decomposition mechanism of polymers useful in photolithography is followed in thermal heating studies. Water desorption studies from RNA strands/fibers is assessed to understand thermal robustness and relative heats of adsorption.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

该奖项由主要研究仪器（MRI）和化学仪器（CRIF）计划资助。 来自纽约州立大学奥尔巴尼分校的Jeremy Feldblyum教授和他的同事John Welch、Rabi Musah、Evgeny Dikarev和Marina Petrukhina获得了一个配备质谱仪（TGA-MS）的热重分析系统。 这台仪器测量样品加热时的重量. 随着蒸汽的释放，样品通过质谱仪进行分析，以确定所释放蒸汽的质量和化学成分。 该数据提供了关于样品本身及其成分（如果是混合物）的身份的信息。 蒸汽可以是提供关于样品的热稳定性的信息的分解产物。 TGA-MS是分析材料的有力工具。 该研究可能影响许多领域，包括有机和无机化学以及聚合物化学。 其中一个例子是合成可用于分离烃类燃料中难以通过蒸馏分离的高价值有机化合物的材料。 在另一个项目中，正在测试储能材料。 用于光刻的新型聚合物的热分解也正在研究中。 当地研究机构，包括大学和学院、商业公司和政府机构（例如：纽约州犯罪实验室（NY State Crime Laboratory）。该仪器为本科生和研究生提供了研究和实验室教学方面的培训机会。这台热重分析仪的购置增强了纽约州立大学奥尔巴尼分校和周边机构的本科生和研究生的研究和教育。用于制备能源相关材料的异金属分子前体正在研究中。 金属有机框架（MOFs）正在测试用于分离高价值有机化合物。 目前正在合成和测试氢捕获等储存材料。 用于光刻的聚合物的分解机理在热加热研究中遵循。 通过评估RNA链/纤维的水解吸研究，了解热稳定性和相对吸附热。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Hetero tri metallic Precursor with 2:2:1 Metal Ratio Requiring at Least a Pentanuclear Molecular Assembly

• DOI: 10.1021/jacs.0c05139
• 发表时间: 2020-07-22
• 期刊: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
• 影响因子: 15
• 作者: Han, Haixiang;Carozza, Jesse C.;Dikarev, Evgeny, V
• 通讯作者: Dikarev, Evgeny, V

Ferrocene metallopolymers of intrinsic microporosity (MPIMs)

固有微孔二茂铁金属聚合物 (MPIM)

• DOI: 10.1039/d1cc05022b
• 发表时间: 2021
• 期刊: Chemical Communications
• 影响因子: 4.9
• 作者: Zhai, Tianran;Ambrose, Kenson;Nyayachavadi, Audithya;Walter, Kelly G.;Rondeau-Gagné, Simon;Feldblyum, Jeremy I.
• 通讯作者: Feldblyum, Jeremy I.

Probing the Edges between Stability and Degradation of a Series of ZnSe‐Based Layered Hybrid Semiconductors

• DOI: 10.1002/admi.202200347
• 发表时间: 2021-07
• 期刊: Advanced Materials Interfaces
• 影响因子: 5.4
• 作者: Mengwen Yan;Jeremy I. Feldblyum;A. Chen;Christopher A. Myers;Gregory John;V. Meyers