Understanding and Controlling Wax-Water Interactions in Pores of Fischer-Tropsch Synthesis Catalysts

了解和控制费托合成催化剂孔隙中的蜡-水相互作用

• 批准号: 1933054
• 负责人: David Hibbitts
• 金额: $ 45万
• 依托单位: University of Florida
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-08-15 至 2023-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1933054&HistoricalAwards=false
• 关键词: Understanding; Controlling; Wax; Water; Interactions

Fischer-Tropsch synthesis (FTS) is a chemical reaction that converts carbon monoxide and hydrogen into water, carbon dioxide, and hydrocarbons. This reaction is a critical and commercially relevant process for upgrading feedstocks such as natural gas (including shale gas resources), coal, and even biomass into useful chemicals and fuels. FTS is catalyzed by metal catalysts (e.g., iron, cobalt or ruthenium) and occurs within very small pores of inexpensive oxide supports (e.g., silica, alumina or titanium dioxide). This research project aims to unravel longstanding mysteries concerning the role of water in FTS catalysis and to leverage those discoveries to create new materials that can lead to more efficient and selective FTS catalysts. The outcomes of this research project will lead to improvements in converting natural gas, coal, and biomass into liquid fuels and chemicals. Furthermore, this project will leverage programs at the University of Florida and Ohio State University to support the involvement of K-12 and undergraduate students, with a focus on under-represented groups, in this research. The water formed during FTS has been shown to increase the rates of FTS as well as shift selectivities towards more desirable long-chain hydrocarbons. However, these promotional effects are not universal, as some studies have shown that water either has a minor impact on FTS rates or causes them to decrease. The effects of water depend on the pore size and hydrophilicity of the oxide support being used in a manner that suggests that water may condense within the pores of the support. These pores are filled with hydrophobic liquid hydrocarbons during FTS, and this hydrophobic environment may assist in capillary condensation of water by effectively reducing the pore size of the support. The first objective of this research project is to determine whether water is condensed within the pores of ruthenium-based FTS catalysts under industrially-relevant conditions by synthesizing and testing Ru catalysts on SBA-15 silica supports. Organosilane surface modifiers will be used to alter the pore size and hydrophobicity of the support. The second objective is to clarify the mechanistic role of water on carbon-oxygen bond activation and carbon-carbon bond formation pathways relevant to the rate and selectivity of FTS. DFT calculations will be performed to study water-assisted reaction pathways with and without extended water solvation networks. The results of this research project will provide additional evidence for the role of water during catalysis and determine whether the influence of water on reaction rates and mechanism requires condensed water phases or simply water vapor. The discovery that water is condensed within the pores of FTS catalysts at industrially-relevant conditions would provide a shift in our understanding of FTS and would have the potential to create new strategies for improving FTS catalyst reactivity, selectivity, and stability.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

费托合成（FTS）是将一氧化碳和氢气转化为水、二氧化碳和烃的化学反应。 该反应是将原料如天然气（包括页岩气资源）、煤、甚至生物质升级为有用的化学品和燃料的关键且商业上相关的过程。 FTS由金属催化剂（例如，铁、钴或钌）并且存在于廉价氧化物载体的非常小的孔内（例如，二氧化硅、氧化铝或二氧化钛）。该研究项目旨在揭开关于水在FTS催化中的作用的长期谜团，并利用这些发现来创造新材料，从而产生更有效和选择性的FTS催化剂。 该研究项目的成果将导致天然气，煤炭和生物质转化为液体燃料和化学品的改进。此外，该项目将利用佛罗里达大学和俄亥俄州州立大学的项目，支持K-12和本科生参与本研究，重点关注代表性不足的群体。在FTS过程中形成的水已经显示出增加FTS的速率以及向更期望的长链烃转移选择性。然而，这些促进作用并不普遍，因为一些研究表明，水对FTS率的影响很小，或导致其下降。水的影响取决于所使用的氧化物载体的孔径和亲水性，其方式表明水可以在载体的孔内冷凝。在FTS期间，这些孔填充有疏水性液态烃，并且这种疏水性环境可以通过有效地减小载体的孔径来帮助水的毛细冷凝。 本研究项目的第一个目标是通过合成和测试SBA-15二氧化硅载体上的Ru催化剂，确定在工业相关条件下，水是否在基于钌的FTS催化剂的孔内冷凝。 有机硅烷表面改性剂将用于改变载体的孔径和疏水性。 第二个目标是阐明水对碳-氧键活化和与FTS的速率和选择性相关的碳-碳键形成途径的机械作用。 将进行DFT计算，以研究水辅助的反应途径与扩展的水溶剂化网络。该研究项目的结果将为水在催化过程中的作用提供额外的证据，并确定水对反应速率和机理的影响是否需要冷凝水相或简单的水蒸气。在工业相关条件下，水在FTS催化剂的孔隙内冷凝的发现将使我们对FTS的理解发生转变，并有可能为改善FTS催化剂的反应性、选择性和稳定性创造新的策略。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Quantifying the fraction and activity of catalytic sites at different surface densities of aminosilanes in SBA-15 for the aldol reaction and condensation

量化 SBA-15 中氨基硅烷不同表面密度下羟醛反应和缩合催化位点的分数和活性

• DOI: 10.1016/j.jcat.2022.08.015
• 发表时间: 2022
• 期刊: Journal of Catalysis
• 影响因子: 7.3
• 作者: Chen, Jee-Yee;Pineault, Hannah;Brunelli, Nicholas A.
• 通讯作者: Brunelli, Nicholas A.