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CAREER: Multi-dimensional synthetic approach toward alkali-transition metal intermetallics guided by theory and in-situ studies

职业：以理论和原位研究为指导的碱金属过渡金属间化合物的多维合成方法

基本信息

批准号：
1944551
负责人：
Julia Zaikina
金额：
$ 68.56万
依托单位：
Iowa State University
依托单位国家：
美国
项目类别：
Continuing Grant
财政年份：
2020
资助国家：
美国
起止时间：
2020-02-01 至 2025-01-31
项目状态：
未结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1944551&HistoricalAwards=false
关键词：
CAREER Multi dimensional synthetic approach

项目摘要

Non-technical summary:Material synthesis and discovery has enabled current technological advances, such as lithium-ion batteries, solar cells, smartphones, microprocessors, medical imaging, and turbines for harnessing wind energy. Despite significant progress in material synthesis, there are many compounds that remain inaccessible by standard synthetic routes. For instance, synthesis of compounds containing ductile and soft alkali metals and powdery non-metals is challenging. Researchers encounter issues with reactants mixing, similar to mixing chocolate chips and cookie dough. With this CAREER award project, supported by the Solid State and Materials Chemistry program in the Division of Materials Research, the principle investigator and her research group develop unique synthetic pathways by utilizing innovative salt-like starting materials. The synthesis is guided by real-time reaction monitoring and theoretical predictions. This approach yields unique alkali metal compounds with potentially useful properties for energy conversion and storage. Additionally, as an education aspect, the PI promotes dissemination of scientific results to the general public, facilitates involvement of undergraduate students into research, and assists graduate students with their job search through video tutorials. These short educational, yet entertaining videos are created as part of the new ICON program (Iowa Chemistry Outreach Network).Technical summary: This CAREER award project, supported by the Solid State and Materials Chemistry program in the Division of Materials Research, advances a synergistic theoretical-experimental synthetic approach to a high level of complexity by aiming at ternary systems with distinctly dissimilar reactivities of elements, such as highly reactive and volatile alkali metals A, refractory and kinetically sluggish transition metals M, and p-block element E. Until now the phase spaces of such systems have remained essentially unexplored, in a stark contrast with similar R-M-E ternary systems (R = rare-earth metal). From the synthetic point of view, elemental alkali metals are challenging precursors. Because of their ductility, volatility, and reactivity, homogeneous mixing of metal/metalloid reactants involving an alkali metal is difficult, while traditional high-temperature treatments, such as arc-melting, are not applicable. This comprehensive experimental approach utilizes salt-like mixable alkali metal hydrides as precursors and is coupled with in-situ reaction monitoring by variable temperature X-ray diffraction and theoretical predictions of structure stability. The research objectives include the targeted and controlled preparation of new ternary compounds, which are unavailable by standard solid state chemistry routes, paving a way to solid state synthesis by design. This research project contributes to the basic knowledge in the field of solid state and materials chemistry, in line with the NSF-DMR program mission. Additionally, as an education aspect, the PI promotes dissemination of scientific results to the general public, facilitates involvement of undergraduate students into research, and assists graduate students in their job search through video tutorials. These short educational, yet entertaining videos are created as part of the new ICON program (Iowa Chemistry Outreach Network).This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术总结：材料的合成和发现使当前的技术进步成为可能，例如锂离子电池、太阳能电池、智能手机、微处理器、医学成像和风能涡轮机。尽管材料合成取得了重大进展，但仍有许多化合物无法通过标准合成路线获得。例如，合成含有韧性和软碱金属和粉状非金属的化合物是具有挑战性的。研究人员遇到了反应物混合的问题，类似于混合巧克力片和饼干面团。在这个由材料研究部固态和材料化学项目支持的CAREER奖项目中，首席研究员和她的研究小组通过利用创新的盐状起始材料开发了独特的合成途径。该合成以实时反应监测和理论预测为指导。这种方法产生独特的碱金属化合物，具有潜在的能量转换和存储的有用性质。此外，作为教育方面，PI促进向公众传播科学成果，促进本科生参与研究，并通过视频教程帮助研究生找工作。这些简短的教育，但娱乐视频是作为新的ICON项目（爱荷华州化学推广网络）的一部分创建的。技术简介:这个CAREER奖项目由材料研究部固态和材料化学项目支持，通过针对具有明显不同反应性元素的三元体系，如高活性和挥发性碱金属a，难熔和动力学迟钝的过渡金属M，推进了一种协同理论-实验合成方法，以达到高水平的复杂性。到目前为止，这种体系的相空间基本上尚未被探索，与类似的R- m -e三元体系（R =稀土金属）形成鲜明对比。从合成的角度来看，单质碱金属是具有挑战性的前体。由于其延展性、挥发性和反应性，涉及碱金属的金属/类金属反应物的均匀混合是困难的，而传统的高温处理，如电弧熔化，则不适用。这种综合的实验方法利用盐类可混合碱金属氢化物作为前体，并结合变温x射线衍射的现场反应监测和结构稳定性的理论预测。研究目标包括定向、可控地制备标准固态化学途径无法获得的新型三元化合物，为设计固态合成铺平道路。该研究项目为固体化学和材料化学领域的基础知识做出了贡献，符合NSF-DMR计划的使命。此外，作为教育方面，PI促进向公众传播科学成果，促进本科生参与研究，并通过视频教程帮助研究生找工作。这些简短的教育，但娱乐视频是作为新的ICON项目（爱荷华州化学推广网络）的一部分创建的。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

期刊论文数量（13）

专著数量（0）

科研奖励数量（0）

会议论文数量（0）

专利数量（0）

From Layered Antiferromagnet to 3D Ferromagnet: LiMnBi-to-MnBi Magneto-Structural Transformation

DOI：
10.1021/acs.chemmater.3c00140
发表时间：
2023-04
期刊：
Chemistry of Materials
影响因子：
8.6
作者：
通讯作者：

Lithium nickel borides: evolution of [NiB] layers driven by Li pressure

DOI：
10.1039/d0qi01150a
发表时间：
2020
期刊：
Inorganic chemistry frontiers
影响因子：
7
作者：
V. Gvozdetskyi;Yang Sun;Xin Zhao;G. Bhaskar;Scott L Carnahan;Colin P. Harmer;Feng Zhang;R. Ribeiro;P. Canfield;Aaron J. Rossini;Caizhuang Wang;K. Ho;J. Zaikina
通讯作者：
V. Gvozdetskyi;Yang Sun;Xin Zhao;G. Bhaskar;Scott L Carnahan;Colin P. Harmer;Feng Zhang;R. Ribeiro;P. Canfield;Aaron J. Rossini;Caizhuang Wang;K. Ho;J. Zaikina

Interplay between Kondo and magnetic interactions in Pr0.75Gd0.25ScGeH

Pr0.75Gd0.25ScGeH 中近藤与磁相互作用之间的相互作用

DOI：
10.1016/j.jallcom.2023.171351
发表时间：
2023
期刊：
Journal of Alloys and Compounds
影响因子：
6.2
作者：
Del Rose, Tyler;Choudhary, Renu;Mudryk, Yaroslav;Haskel, Daniel;Pathak, Arjun K.;Bhaskar, Gourab;Zaikina, Julia V.;Johnson, Duane D.;Pecharsky, Vitalij K.
通讯作者：
Pecharsky, Vitalij K.

Topochemical Deintercalation of Li from Layered LiNiB: toward 2D MBene