Achiral and Chiral Nanographene Synthesis Using an Alkyne Linchpin Strategy

使用炔烃关键策略合成非手性和手性纳米石墨烯

• 批准号: 2102107
• 负责人: Sean Casey
• 金额: $ 48.31万
• 依托单位: Board of Regents, NSHE, obo University of Nevada, Reno
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2021
• 资助国家: 美国
• 起止时间: 2021-09-01 至 2024-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2102107&HistoricalAwards=false
• 关键词: Achiral; Chiral; Nanographene; Synthesis; Using

With the support of the Chemical Synthesis Program in the Division of Chemistry, Wesley Chalifoux of the University of Nevada, Reno is studying ways to make nanographenes from small, precise, molecular building blocks. Nanographenes are flat sheets of carbon atoms that mimic small sections of graphene. The optoelectronic properties of nanographenes make them attractive materials in applications such as organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), and organic solar cells. The Chalifoux research group’s efforts to develop new ways to make these molecules are supporting the design of next-generation devices. Dr. Chalifoux and his team of students are converting modifiable chemical building blocks to nanographenes under mild conditions and monitoring how specific changes in the building blocks tune the characteristics of the nanographenes, including their three-dimensional shape and optical properties. These activities are also supporting the engagement of high school students in chemical research to encourage their engagement in science and to support their progression towards successful science, technology, engineering, and mathematics (STEM) careers.Wesley Chalifoux and his research team are advancing the use of alkyne benzannulation as a mild and versatile strategy for preparing nanographenes with tunable optical properties. The use of high-energy alkyne-containing precursors allows for the use of mild benzannulation conditions that support expanded functional group tolerance and provide access to a variety of nanographene structures that cannot be achieved using other methods. The Chalifoux group will apply this strategy to the synthesis of highly contorted and chiral nanographene molecular scaffolds that exhibit circularly polarized light characteristics and can be envisioned in variety of chiroptic applications such as liquid crystal displays, chiral sensing, holographic displays, three-dimensional displays, and other information technologies. The development of new C-H functionalization strategies will also be explored in combination with benzannulation to provide new and potentially facile routes to larger nanographenes that exhibit significant red shifts in the absorption and emission spectra. These activities are synergistically providing training in organic synthesis and advanced analytical techniques for a diverse cohort of graduate, undergraduate, and high school students.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在化学系化学合成项目的支持下，内华达州大学里诺分校的Wesley Chalifoux正在研究从小的、精确的分子构建块制造纳米石墨烯的方法。纳米石墨烯是模仿石墨烯的小部分的碳原子的平板。纳米石墨烯的光电性能使其在有机发光二极管（OLED）、有机场效应晶体管（OFFET）和有机太阳能电池等应用中成为有吸引力的材料。Chalifoux研究小组努力开发制造这些分子的新方法，支持下一代设备的设计。Chalifoux博士和他的学生团队正在温和条件下将可修饰的化学构建块转化为纳米石墨烯，并监测构建块的特定变化如何调整纳米石墨烯的特性，包括其三维形状和光学特性。这些活动还支持高中生参与化学研究，鼓励他们参与科学，并支持他们走向成功的科学，技术，工程和数学（STEM）职业生涯。Wesley Chalifoux和他的研究团队正在推进使用炔苯并环化作为一种温和的多功能策略，用于制备具有可调光学特性的纳米石墨烯。使用高能含炔前体允许使用温和的苯并环化条件，其支持扩大的官能团耐受性并提供使用其他方法无法实现的各种纳米石墨烯结构的途径。Chalifoux小组将把这一策略应用于高度扭曲和手性纳米石墨烯分子支架的合成，这些纳米石墨烯分子支架具有圆偏振光特性，并且可以设想用于各种手性应用，如液晶显示器，手性传感，全息显示器，三维显示器和其他信息技术。新的C-H官能化策略的开发也将与benzannulation结合进行探索，以提供新的和潜在的简便路线，以获得在吸收和发射光谱中表现出显着红移的较大纳米石墨烯。这些活动协同为研究生、本科生和高中生提供有机合成和先进分析技术的培训。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。