CAREER: Dynamics and structure of comb polymer elastomers

职业：梳状聚合物弹性体的动力学和结构

• 批准号: 2338550
• 负责人: Amanda Marciel
• 金额: $ 67.04万
• 依托单位: William Marsh Rice University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2024
• 资助国家: 美国
• 起止时间: 2024-09-01 至 2029-08-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2338550&HistoricalAwards=false
• 关键词: CAREER; Dynamics; structure; comb; polymer

NON-TECHNICAL SUMMARY:Polymer networks consisting of branch polymer architectures (polymers with sidechains attached to linear backbones) can be used to independently tune material stiffness and elasticity. Supersoft and hyper-elastic solvent-free materials offer potentially transformative opportunities for emerging applications in stretchable electronics and biomaterials. Controlling network properties, however, remains a significant challenge due to synthetic limitations associated with the underlying branch polymer architecture. This research project will directly investigate the relationship between network structure, mechanics, and branch polymer architecture by developing synthetic methods to precisely control branch length, spacing between branches, and the chemistry that links branches together. Light scattering and rheological characterization techniques will be used to measure network properties under varying solution and bulk conditions. The insights gained from this research will address a critical knowledge gap in understanding the mechanical properties of topologically complex polymer networks, including those that depend on deformation history. The results from this project are expected to inform design of tunable materials with enhanced processing efficiency and predictable mechanical properties for applications that use films, fibers, and foams. Outreach efforts will be developed to increase intellectual diversity and the number of underrepresented scientists in soft matter research by creating innovative symposia focused on community college teachers and students and on cross-sector collaboration between academia, industry, and national laboratories. TECHNICAL SUMMARY:The molecular design of branch polymer elastomers offers a potentially transformative route towards synthetic networks with gel-like softness, high elasticity, and enhanced strain-adaptive stiffening for applications ranging from stretchable electronics to biomimetic tissues. The efficacy of these materials is dependent on the underlying polymer topology (i.e., linear, comb, and bottlebrush polymers) of the cross-linked network. For example, comb and bottlebrush elastomers have unprecedented mechanical properties because stiffness and elasticity can be decoupled by varying sidechain length, sidechain spacing, and cross-link spacing. Due to synthetic limitations, however, the cross-link and sidechain uniformity and spacing are challenging to control precisely and characterize experimentally. Thus, there remains a critical need for an experimental platform with precise control of cross-link and sidechain spacing to elucidate structure-function relationships in branch polymer elastomers. This CAREER project will address these outstanding challenges through investigation of model comb polymers with precise topological parameters to develop a fundamental understanding of the effects of cross-link and sidechain uniformity on elastomer formation, mechanical properties, and structure, thus establishing a new paradigm in elastomer design. Expertise in polymer synthesis, X-ray/neutron scattering, solution dynamics, and STEM outreach will be integrated to address three research aims and one educational aim: (1) determine the role of comb polymer topology on elastomer formation and dynamics, (2) understand the effects of comb polymer topology on elastomer mechanics, (3) characterize the effects of comb polymer topology on elastomer structure, and (4) establish new symposia and research opportunities for undergraduates to increase intellectual diversity and support underrepresented scientists in soft matter research..This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术总结：由分支聚合物结构（侧链连接到线性骨架的聚合物）组成的聚合物网络可用于独立调节材料刚度和弹性。超软和超弹性无溶剂材料为可拉伸电子产品和生物材料的新兴应用提供了潜在的变革机会。然而，由于与潜在的分支聚合物结构相关的合成限制，控制网络性质仍然是一个重大挑战。本研究项目将通过开发合成方法来精确控制分支长度、分支之间的间距以及将分支连接在一起的化学反应，直接研究网络结构、力学和分支聚合物结构之间的关系。光散射和流变表征技术将用于测量不同溶液和本体条件下的网络特性。从这项研究中获得的见解将解决在理解拓扑复杂聚合物网络的机械性能方面的关键知识差距，包括那些依赖于变形历史的知识。该项目的结果有望为可调材料的设计提供信息，这些材料具有更高的加工效率和可预测的机械性能，适用于使用薄膜、纤维和泡沫的应用。将开展外联工作，通过创建创新的研讨会，重点关注社区学院的教师和学生，以及学术界、工业界和国家实验室之间的跨部门合作，增加知识多样性和软物质研究中代表性不足的科学家的数量。 技术总结：分支聚合物弹性体的分子设计为合成网络提供了一条潜在的变革路线，该合成网络具有凝胶状柔软性、高弹性和增强的应变适应性硬化，适用于从可拉伸电子产品到仿生组织的应用。这些材料的功效取决于潜在的聚合物拓扑结构（即，线性、梳状和瓶刷状聚合物）。例如，梳子和瓶刷弹性体具有前所未有的机械性能，因为刚度和弹性可以通过改变侧链长度、侧链间距和交联间距来解耦。然而，由于合成的限制，交联和侧链的均匀性和间距是具有挑战性的精确控制和实验表征。因此，仍然迫切需要一种精确控制交联和侧链间距的实验平台，以阐明分支聚合物弹性体中的结构-功能关系。该CAREER项目将通过研究具有精确拓扑参数的梳型聚合物模型来解决这些突出的挑战，以基本了解交联和侧链均匀性对弹性体形成，机械性能和结构的影响，从而建立弹性体设计的新范式。聚合物合成，X射线/中子散射，溶液动力学和STEM外展的专业知识将被整合，以解决三个研究目标和一个教育目标：（1）确定梳形聚合物拓扑结构对弹性体形成和动力学的作用，（2）理解梳形聚合物拓扑结构对弹性体力学的影响，（3）表征梳形聚合物拓扑结构对弹性体结构的影响，和（4）为大学生建立新的研讨会和研究机会，以增加智力多样性和支持在软物质研究中代表性不足的科学家。该奖项反映了NSF的法定使命，并被认为是值得通过使用基金会的知识价值和更广泛的影响审查标准进行评估的支持。