Fine coatings of bio-seramics with using well controlled thermal plasmas

使用良好控制的热等离子体进行生物陶瓷的精细涂层

• 批准号: 17204053
• 负责人: FUKUMASA Osamu
• 金额: $ 31.12万
• 依托单位: Yamaguchi University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 2005
• 资助国家: 日本
• 起止时间: 2005 至 2007
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-17204053/
• 关键词: plasma jet; thermal plasma spraying; functionally graded coating; bio-ceramics spraying; hydroxyapatite; control of fine structure; carbon nanostructures; synthesis of TiO_2; 熱プラズマプロセス; プラズマ溶射; フェライト合成; MgO溶射膜

With the use of the well-controlled thermal plasma reactor based on the newly designed forced constricted type dc plasma jet generator, application feasibility for advanced materials fine process is studied, mainly functionally graded coatings (FGC) of hydroxyapatite (HAP). Findings are as follows:1. The image spectroscopic system composed of a double wavelength optical system and the gated ICCD camera has been developed. This system can measure two dimensional temperature distribution and parameters of injected spraying particles. Relationship between parameters of injected spraying particles and quality of prepared films is discussed.2. Preparation of Ti-HAP FGC films are studied under various spraying conditions. The adhesion strength, the Vickers hardness, c-axis orientation and the porosity of prepared FGC films are well controlled with spraying conditions. Simulated body fluid test of HAP coatings is also discussed and apatite is newly formed on the surface of the coatings.3. A continuous synthesis method to produce carbon nanofibers (CNFs) including multi-walled carbon nanotubes is studied. CNFs production using catalyst powders (Fe, Ni) is more enhanced compared to that using only CH_4/H_2 gas mixtures.4. Plasma spray gun has been newly designed as dual anode type plasma spray gun which can generate stable and high power plasma jets for a long time at various operating conditions. Using this, under laminar plasma jets in the air, TiO_2 powders with anatase and rutile types mixtures are directly and effectively synthesized from raw Ti powders.

利用新设计的受控热等离子体反应器，研究了以羟基磷灰石(HAP)功能梯度涂层(FGC)为核心的先进材料精细加工的可行性。主要研究成果如下：1.研制了由双波长光学系统和门控ICCD摄像机组成的图像光谱系统。该系统可以测量喷雾颗粒的二维温度分布和参数。讨论了喷雾粒子参数与成膜质量的关系。研究了不同喷涂条件下Ti-HAP FGC膜的制备。制备的FGC薄膜的结合强度、维氏硬度、c轴取向和孔隙率随喷涂条件的变化而得到很好的控制。对羟基磷灰石涂层进行了模拟体液试验，涂层表面新生成了磷灰石。研究了一种连续合成含多壁碳纳米管的碳纳米纤维的方法。与仅使用CH_4/H_2混合气体相比，使用催化剂粉末(Fe、Ni)可以更好地提高CNFS的产量。等离子喷枪是一种新型的双阳极型等离子喷枪，可以在各种工况下长时间产生稳定的、高功率的等离子喷枪。利用这种方法，在空气中的层流等离子体射流作用下，以钛粉为原料，直接有效地合成了锐钛矿型和金红石型混合型的二氧化钛粉末。

项目成果

Production of High Quality Ti-HAP Functionally Graded Coating Using Well-Controlled Thermal Plasmas(II)-Relationship between Quality of Prepared Films and Plasma Jet Temperature-

利用良好控制的热等离子体生产高质量Ti-HAP功能梯度涂层(II)-制备薄膜的质量与等离子体射流温度之间的关系-

• 发表时间: 2008
• 作者: Takao Fuji;Toshinori Suzuki;Y.Yamatan;日高 洋;Takao Fuji and Toshinori Suzuki;M.Kurita;O. Fukumasa;Toshinori Suzuki;日高 洋;Toshinori Suzuki;O. Fukumasa;O.Fukumasa;日高 洋;Toshinori Suzuki;K.Osaki;Toshinori Suzuki;H. Hidaka;T. Toda;Toshinori Suzuki;H. Hidaka;小城 吉寛,高口 博志,莫 宇翔,鈴木 俊法;Y. Yoshihara;小城 吉寛,高口 博志,鈴木 俊法;菊池麻希子;T. Toda;鈴木 俊法;瀧口 愛;K. Akimoto;鈴木 俊法;T. Toda;日高 洋;藤 貴夫,堀尾 琢哉,鈴木 俊法;K. Akimoto;瀧口 愛;鈴木 俊法;穐本和樹;菊池麻希子;鈴木 俊法;堀江憲路;吉原雄一;Toshinori Suzuki;Toshinori Suzuki;K. Horie;戸田剛史;Toshinori Suzuki;Masahiro Kou;M. Kikuchi;Toshinori Suzuki;Takafumi Toda
• 通讯作者: Takafumi Toda

プラズマ反応溶射法によるTiO_2粉末の即時合成-反応場のガス冷却効果-

等离子反应喷涂即时合成TiO_2粉体-反应场气体冷却效果-

• 发表时间: 2005
• 作者: Yoshiichi Suzuki;Takuya Horio;Yoshihiro Ogi;Hiroshi Kohguchi;Toshinori Suzuki;奥 瑞希,大下 慶次郎,岩崎 純史,西澤 潔,鈴木 俊法;武井信裕;鈴木 喜一,鈴木 俊法,;藤本聡;鈴木 喜一,鈴木 俊法;大崎堅;鈴木 俊法;Y. Yamatan;鈴木 俊法;M. Kurita;鈴木 俊法;大崎堅;鈴木 喜一,鈴木 俊法;Y. Yamatani;奥 瑞希,大下 慶次郎,岩崎 純史,西澤 潔,鈴木 俊法;M. Kurita;西澤 潔,大下 慶次郎,鈴木 俊法;赤畑海山;岩崎 純史,;大崎堅
• 通讯作者: 大崎堅

プラズマジェットによるMgO溶射膜の作製と水素添加効果

利用等离子射流和加氢效应制备MgO喷涂膜

• 发表时间: 2005
• 作者: Yoshiichi Suzuki;Toshinori Suzuki;Toshinori Suzuki;赤畑海山
• 通讯作者: 赤畑海山

プラズマジェットによるカーボンナノ構造体の連続形成

通过等离子体射流连续形成碳纳米结构

• 发表时间: 2005
• 作者: Mizuki Oku;Keijirou Ohshimo;Atsushi Iwasaki;Kiyoshi Nishizawa;Toshinori Suzuki;山谷陽一
• 通讯作者: 山谷陽一

Continuous synthesis of carbon nanoclusters using well-controlled thermal plasmas

使用良好控制的热等离子体连续合成碳纳米簇

• 发表时间: 2008
• 期刊: Surface & Coatings Technology 202
• 作者: 上田真也*;小淵保幸;高橋幸弘;坂野井健;島崎準一;荘司泰弘;吉田和哉;Takao Fuji and Toshinori Suzuki;H.Hidaka;T. Ohishi
• 通讯作者: T. Ohishi