Development on a novel catalysis based on the structural fluctuation of metal cluster catalysts
Development on a novel catalysis based on the structural fluctuation of metal cluster catalysts
批准号:
21850001
负责人:
TSUNOYAMA Hironori
金额:
$1.93万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Research Activity Start-up
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010
中文摘要
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英文摘要
The effect of size in the aerobic oxidation catalysis of Au clusters stabilized by PVP has been investigated in the atomic resolution. It is concluded that (1) only the Au clusters smaller than 70-mer are active in the catalysis and (2) the activity is originated from the excess negative charge on the Au clusters which is donated by PVP. It was found that the microwave irradiation drastically accelerates the aerobic oxidation catalysis of Au11 supported on mesoporus silica.
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現代化学増刊44 16章「金属ナノクラスターの化学」
现代化学特别版44第16章“金属纳米团簇的化学”
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[角山寛規, 佃達哉]
通讯作者:
佃達哉
Exploring Magic Numbersin Au Clusters Stabilized by PVP
探索 PVP 稳定的金簇中的神奇数字
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[宮村浩之, 小林修, Sudhir M.Hande,上崎春陽,塚野千尋,竹本佳司, 前田和彦, 角山寛規]
通讯作者:
角山寛規
Efficient and Selective Epoxidation of Styrene with TBHP Catalyzed by Au25 Clusterson
Au25 Clusterson 催化 TBHP 高效选择性环氧化苯乙烯
DOI:
--
发表时间:
2010
期刊:
Hydroxyapatite, Chem.Commun. Vol.46
影响因子:
--
作者:
[上村亮輔, 木下英典, 三浦勝清, 島田林太郎, 劉永梅,角山寛規,秋田友樹,佃達哉]
通讯作者:
劉永梅,角山寛規,秋田友樹,佃達哉
DOI:
10.1021/ja102934q
发表时间:
2010-06-16
期刊:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
影响因子:
15
作者:
[Lopez-Acevedo, Olga, Tsunoyama, Hironori, Aikens, Christine M.]
通讯作者:
Aikens, Christine M.
DOI:
10.1039/b921082b
发表时间:
2010-01-01
期刊:
CHEMICAL COMMUNICATIONS
影响因子:
4.9
作者:
[Liu, Yongmei, Tsunoyama, Hironori, Tsukuda, Tatsuya]
通讯作者:
Tsukuda, Tatsuya
共 20 条
Development on fine synthesis method for binary nanocluster catalysts with controlled size and chemical composition
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批准号:23750001
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项目类别:Grant-in-Aid for Young Scientists (B)
-
资助金额:$2.91万
-
财政年份:2011
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负责人:TSUNOYAMA Hironori
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依托单位:
海外基金