Coating Process of iron siliside on iron for oxidation resistance

铁上硅化铁的抗氧化涂层工艺

• 批准号: 10555256
• 负责人: SUZUKI Ryosuke
• 金额: $ 5.89万
• 依托单位: KYOTO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B).
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 2000
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/en/grant/KAKENHI-PROJECT-10555256/
• 关键词: iron silicide; oxidation resistance; molten salt; surface treatment; high temperature oxidation; steel sheet; concentration gradience; silicon; 耐酸化性被膜; オゾン酸化; 高温X線回折

A process to coat Fe_3Si-SiO_2 composite film on the mild steel was developed for corrosion and oxidation resistance. Using the molten salt, the iron silicide was deposited on the iron sheet, and its surface was then oxidized by ozone gas at the low temperature.The molten salt consisting of KCl-NaCl-NaF-Si-SiO_2-Na_2SiF_6 was chosen because of the minimized evaporation and oxidation, and stability in air. Electroless coating on the pure iron and on the mild steel formed the smooth Fe_3Si layer over 100μm thick within 1 hour. The molten salt was trapped at the interface between silicide layer and the substrate when the growth was so rapid. No defect was fund when the iron-silicon alloy was supplied as the substrate. These findings showed that such a rapid supply of silicon ions from pure silicon to the molten salt caused the defects. The coating mechanism consisted of disproportional reaction and diffusion. Considering the growth mechanism, the α-(iron, silicon) alloy was successfully coated on iron and the layer did not contain any defects, when the aluminum-silicon liquid alloy was used instead of pure silicon. Subsequently the molten salt was replaced to the conventional salt containing pure silicon. The layer had the concentration gradient in the layer and no defects at the interface. The healthy coating was achieved by alloying silicon to control activity, or by reducing silicon ion concentration in the salt.Similarly, the silicide layer for oxidation resistance was formed on the refractory metals such as molybdenum, niobium and nickel. A new finding was that ozone gas blowing could form Cr_2O_3 layer by producing the molten CrO_3.

开发了一种在低碳钢上涂覆Fe_3Si-SiO_2复合膜的工艺，以提高其耐腐蚀性和抗氧化性。利用熔盐将硅化铁沉积在铁片上，然后在低温下用臭氧气体氧化其表面。由于蒸发和氧化最小化以及在空气中的稳定性，选择由KCl-NaCl-NaF-Si-SiO_2-Na_2SiF_6组成的熔盐。化学镀在纯铁和低碳钢上1小时内形成厚度超过100μm的光滑Fe_3Si层。当生长如此迅速时，熔盐被捕获在硅化物层和衬底之间的界面处。当提供铁硅合金作为基材时，没有发现任何缺陷。这些发现表明，硅离子从纯硅到熔盐的快速供应导致了缺陷。涂层机理包括歧化反应和扩散。考虑到生长机制，当使用铝硅液态合金代替纯硅时，α-（铁、硅）合金成功地沉积在铁上，且涂层中不存在任何缺陷。随后将熔盐替换为含纯硅的常规盐。该层具有层内浓度梯度且界面处无缺陷。通过将硅合金化以控制活性，或通过降低盐中的硅离子浓度来实现健康的涂层。同样，在钼、铌和镍等难熔金属上形成抗氧化的硅化物层。一个新的发现是吹臭氧气体可以通过产生熔融的CrO_3而形成Cr_2O_3层。

项目成果

R.O.Suzuki: "Electroless Coating of Fe_3Si on Steels in the Moleten Salt"Proc.of 6th Intern.Conf.on Molten Slags, Fluxes and Salts. 22_360.1-16 (2000)

R.O.Suzuki：“铁盐中钢上 Fe_3Si 的化学镀”Proc.of 6th Intern.Conf.on Molten Slags, Fluxes and Salts。

R.O.Suzuki: "Electroless Coating of Fe_3Si on Steel in the Molten Salt"steel research. 71. 130-137 (2000)

R.O.Suzuki：“钢上熔盐中 Fe_3Si 的化学镀层”钢研究。

R.O.Suzuki: "Growth of Fe_3Si Layer Deposited from the Molten Salt"steel research. 71. 138-143 (2000)

R.O.Suzuki：“从熔盐沉积的 Fe_3Si 层的生长”钢研究。

R.O.Suzuki: "MoSi_2 Coating on Molybdenum Using Molten Salt"J.Alloys and Compounds. 306. 285-291 (2000)

R.O.Suzuki：“使用熔盐在钼上进行 MoSi_2 涂层”J.合金和化合物。

R.O.Suzuki: "Electroless Coating of Fe_3Si on Steels in the Moleten Salt"Proc.of 6th Intern.Conf.on Molten Slags,Fluxes and Salts. 180.1-180.16 (2000)

R.O.Suzuki：“铁盐中钢上 Fe_3Si 的化学镀”Proc.of 6th Intern.Conf.on Molten Slags, Fluxes and Salts。