Study on structure and Function of Structure Controlled Polymer prepared from Self-assemble Amphiphilic Monomer

以苯乙烯和长烷基氯化铵组成的自组装两亲性单体为原料，经低能电子束辐照制备了垂直于膜表面的双层堆叠结构的各向异性聚合物薄膜。这种聚合方法将两亲性单体的分子排列固定在聚合物中，称为“自组装聚合”。本研究采用DSC-XRD和DSC-FTIR同时研究了两亲性单体、单体模型材料和各向异性聚合物的热行为。为了使自组装聚合发生，分子排列是最重要的。数据。在熔解后的近晶相，苯乙烯单元的排列波动减小。所制得的各向异性聚合物作为离子选择电极具有较高的灵敏度和选择性。

The anisotropic polymer film, in which the stacked bilayer structure was perpendicular to the film surface, was prepared from the self-assemble amphiphilic monomer consisted of styrene and long alkyl ammonium chloride by the irradiation of low energy electron beam. The molecular arrangement of amphiphilic monomer was fixed in the obtained polymer by this polymerization method called as "the self-assemble polymerization". In this study, thermal behavior of amphiphilic monomer, monomer model material and anisotropic polymer were investigated by the simultaneous DSC-XRD and DSC-FTIR methods. In order to occur the self-assemble polymerization, the molecular arraignment is most important. The data. The fluctuation of arraignment in styrene units became lower at the smectic phase immediately after the melting. The obtained anisotropic polymer had high sensitivity and selectivity as an ion selective electrode.