Excess electrons, solvation and electron-transfer reaction in ionic liquids
Excess electrons, solvation and electron-transfer reaction in ionic liquids
批准号:
17073010
负责人:
TAKAHASHI Kenji
金额:
$30.98万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research on Priority Areas
财政年份:
2005
资助国家:
日本
项目状态:
已结题
起止时间:
2005 至 2009
中文摘要
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英文摘要
We have established a formation method of excess electron in ionic liquid using photo-ionization, and shed a light on the reaction dynamics and kinetics of solvated electron with several different solutes. The spectra of solvated electrons in ionic liquids are located in near infrared region. It has been found that there is a strong Coulombic screening effect on the ionic reactions in ionic liquids. Using twin-pulse laser excitation method, reaction dynamics of excited-state radical in ionic liquids has been precisely examined.
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Reactions of Excited-Benzophenone Ketyl Radical in a Room Ternperature lonic Liquid
室温离子液体中激发的二苯甲酮羰基自由基反应
DOI:
--
发表时间:
2010
期刊:
Physical Chemistry Chemical Physics 12
影响因子:
--
作者:
[Kenji Takahashi, Hiroaki Tezuka, Shingo Kitamura, Takafumi Seto, Toshifumi Satoh, Ryuji Katoh]
通讯作者:
Ryuji Katoh
Detrapping of solvated electrons in an ionic liquid with 532 and 1064nm pulses
使用 532 和 1064 nm 脉冲释放离子液体中的溶剂化电子
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[宮田敦彦, 小嶋映二, 植田浩明, 上田寛, 嶽山正二郎, Kenji Takahashi]
通讯作者:
Kenji Takahashi
Effect of mass transfer on electrochemical carboxylation of aromatichalides in ionic liquid compressed with carbon dioxide
二氧化碳压缩离子液体中传质对芳香卤化物电化学羧化的影响
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[Yusuke Hiejima, Akihiro Uda, Masahiro Hayashi, Seiko Oya, Kenji Takahashi]
通讯作者:
Kenji Takahashi
Dtrapping of solvated electrons in an ionic liquid with 532 and 1064 nm pulses
使用 532 和 1064 nm 脉冲捕获离子液体中的溶剂化电子
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[嶽山正二郎, 小嶋映二, 澤部博信, Kenji Takahashi]
通讯作者:
Kenji Takahashi
Photo-detraping of solvated electrons in an ionic liquid
离子液体中溶剂化电子的光捕获
DOI:
--
发表时间:
2009
期刊:
Rad. Phys. Chem. 78
影响因子:
--
作者:
[K. Takahashi, K. Suda, T. Seto, Y. Katsumura, R. Katoh, R.A. Crowell, J.F. Wishart]
通讯作者:
J.F. Wishart
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