Design and Development of Multimetallic Reagents and Their Application in Synthetic Reactions

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This research program dealt with synergistic effects of various combinations of transition and main group metals on the catalyses for synthetic organic transformations. We focused, in particular, on transition metal/main group metal, or transition metal/transition metal cooperative catalysts upon carbon-carbon bond formation reactions. Herein are described representative results of the research program: iron-catalyzed selective biaryl cross-coupling and iron-catalyzed cross-coupling reaction of haloalkanes with various organometallic reagensts, including organomagnesium, zinc, boron, and aluminum compounds.