Reversible Addition Fragmentation Chain Transfer (RAFT) Free Radical Copolymerizations of Various Monomers

各种单体的可逆加成断裂链转移 (RAFT) 自由基共聚

• 批准号: LX0453282
• 负责人: Prof Thomas Davis
• 金额: $ 4.68万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: Linkage - International
• 财政年份: 2004
• 资助国家: 澳大利亚
• 起止时间: 2004-01-01 至 2005-03-30
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/LX0453282
• 关键词: Reversible; Addition; Fragmentation; Chain; Transfer

The proposed project will investigate the structure and properties of statistical copolymers prepared via living free radical polymerization. We will study the characteristics of a wide variety of Reversible Addition Fragmentation Chain Transfer (RAFT) copolymerizations using a range of monomers, including those interesting for biomedical and material science applications. We expect to gain a deeper understanding of the influence of the RAFT process on the kinetics and mechanism of copolymerization and the properties of the resulting polymers in order to tailor specific polymer materials for biomedial applications.

本计画将探讨以活性自由基聚合制备统计共聚物之结构与性质。我们将研究各种可逆加成断裂链转移（RAFT）共聚使用一系列单体，包括那些有趣的生物医学和材料科学应用的特点。我们期望获得更深入的了解RAFT过程的动力学和共聚反应机理的影响和所得聚合物的性质，以定制特定的聚合物材料的生物医学应用。