All-Solid State Micro-Secondary Battery

全固态微二次电池

• 批准号: 07455145
• 负责人: BABA Mamoru
• 金额: $ 4.99万
• 依托单位: Iwate University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07455145/
• 关键词: secondary battery; lithium-ion battery; molecular dynamics; vanadium oxide; lithium phosphate; solid electrolyte; all-solid-state battery; thin-film type battery; 薄型二次電池; スパッタリング法; リチウム二次電池

1.Preparation and characterization of all-solid and thin-film type secondary batteryThe all-solid-state secondary battery which is composed of | V_2O_5 catrode/Li_3PO_<4-X>N_X electrolyte / Li_XV_2O_5 anode | was successfully fabricated using an RF magnetron sputtering method. This thin-film type of Li-ion battery exhibited good performances in repetion, self-discharge and reproducible properties. This inticates that the present battery can be used as power sources with quite a high reliability.2.Basic experiments for a micro-secondary batteryThe thin-film lithium-ion battery fabricated on a Si wafer with a buffered layr of WSi_2 operated successfully. It means that this type of lithium-ion rechargeable battery can be used compatibly with Si micro-electronics as a micro-secondary battery for driving a various type of LSI chipps.3.Computer simulation of Li ions in V_2O_5matrices using the molecular dynamics (MD) methodBy optimization of potential parameters, we could stabilize the V_2O_5 lattices of a complicated layr structure at the first time. As a result, it is possible to simulate the movement of indivisual atoms in a real time and also to discuss the lattice stability by analyzing a structural factor.4.Consideration of a composite type battery loaded with a Si solar cellIt was found that the present Li-ion battery can be quite easily and effectively charged by the Si solar cell. This means that AC 100V power supply is not necessary for charging thie battey.5.It will be necessary to develope a technique for getting a large-area battery and a layr-stacking technique for serial and parallel connections between thin film batteries, as well as a surface coating technique for passivation and isolation between them.

1.全固态薄膜型二次电池的制备与表征全固态二次电池由|V_2O_5阴极/Li_3PO_N_X<4-X>电解质/ Li_XV_2O_5阳极|使用RF磁控溅射方法成功地制造。该薄膜型锂离子电池具有良好的重复性、自放电性和可重复性。2.微型二次电池的基础实验在硅基片上以WSi_2为缓冲层制备的薄膜锂离子电池成功地工作。这意味着这种锂离子二次电池可以与硅微电子兼容地用作驱动各种类型LSI芯片的微型二次电池。3. Li离子在V_2O_5基体中的分子动力学（MD）模拟通过势参数的优化，首次实现了复杂层状结构V_2O_5晶格的稳定化。因此，可以真实的模拟单个原子的运动，并通过分析结构因素来讨论晶格稳定性。4.负载硅太阳能电池的复合型电池的考虑发现，本发明的锂离子电池可以通过硅太阳能电池非常容易且有效地充电。这意味着交流100 V电源是不必要的充电thie电池。5.这将是必要的开发技术，以获得一个大面积的电池和层堆叠技术之间的串联和并联连接的薄膜电池，以及表面涂层技术的钝化和隔离它们之间。

项目成果

柏葉 安兵衛 他: "低温基板上へのカドミウムースズ酸化物透明電極膜の作成とその諸特性" 真空. 第39巻 第7号. 339-345 (1996)

Yasubei Kashiwaba 等：“低温基底上氧化镉透明电极薄膜的制备及其性能”，真空，第 39 卷，第 7. 339-345 期。

N.Kumagai et al.: "Physical and Electrochemical Characterization of Quaternary Li-Mn-V-O Spinel as Positive Materials for Rechargeable Lithium Batteries" J.Electrochemical Society. Vol.143 No.3. 1007-1013 (1996)

N.Kumagai 等人：“作为可充电锂电池正极材料的四元 Li-Mn-V-O 尖晶石的物理和电化学特性”J.Electrochemical Society。

K.Nishidate and M.Baba et al.: "A cellular-automata simulation program for a silicone anisotropic super-micro-etching process in aqueous KOH" Computers in Physics. Vol.12 No.1. 88-93 (1998)

K.Nishidate 和 M.Baba 等人：“KOH 水溶液中有机硅各向异性超微蚀刻过程的元胞自动机模拟程序”物理计算机。

N.Kumagai and M.Baba et al.: "Intercalation of Lithium in RF Sputtered Niobium Oxide Film as Electrode Material for Lithium-Ion-Batteries" Journal of Power Sources. Vol.54. 175-179 (1995)

N.Kumagai 和 M.Baba 等人：“作为锂离子电池电极材料的射频溅射氧化铌薄膜中锂的嵌入”《电源杂志》。

N.Kumagai et al.: "Physical and Electrochemical Characterization of Quaternary Li-Mn-V-O Spinel as Positive Materials for Rechargeable Lithium Batteries" J.Electrochem.Soc.Vol.143, NO.3. 1007-1013 (1996)

N.Kumagai 等人：“作为可充电锂电池正极材料的四元 Li-Mn-V-O 尖晶石的物理和电化学特性”J.Electrochem.Soc.Vol.143，NO.3。