Development of Monitoring System of Electrochemical Reaction by Using Surface Plasm on Resonance

表面等离子体共振电化学反应监测系统的研制

• 批准号: 07555266
• 负责人: UOSAKI Kohei
• 金额: $ 8.9万
• 依托单位: HOKKAIDO UNIVERSITY
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (A)
• 财政年份: 1995
• 资助国家: 日本
• 起止时间: 1995 至 1997
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-07555266/
• 关键词: surface plasmon; Raman Spectroscopy; electrode reaction; self-assembled monolayr; surface structure; 電極表面班応; 表面プラズモン

This project was carried out to construct an electrode surface reaction monitoring system utilizing surface plasmon resonance. During the last 3 years, we have constructed 1."Surface Plasmon Rcsonance System" which can measure the thickness of monolayr on the electrode very accurately with relatively high time resolution and 2. "Plasmon Excited Raman Measuring System" which utilizes the enhancement of Raman Scattering by plasmon excitataion. These systems were applied to monitor the self-assembly process of alkanethiols in situ in real time.

该项目是为了构建电极表面反应监测系统，利用表面等离子体共振。在过去的三年中，我们构建了1.“表面等离子体的RCSONANESS系统”，该系统可以非常准确地测量电极上的单片厚度，并使用相对较高的时间分辨率和2个。“等离子体激发的拉曼测量系统”，该系统利用了等离子激发的拉曼散射增强拉曼散射。这些系统用于实时监测烷硫醇的自组装过程。

项目成果

R.Yamada: "In situ, Real time monitoring of the self-assembly process of decanethiol on Au(111) in liquid phase. A scanning tunneling microscopy investigation" Langmuir. 13/20. 5218-5221 (1997)

R.Yamada：“液相中癸硫醇在 Au(111) 上的自组装过程的原位实时监测。扫描隧道显微镜研究”Langmuir。

S. Nakabayashi: "Dissociative Adsorption Dynamics of Formaldehyde on a Platinum Electrode Surfaces ; One-Dimensional Domino?" Chem. Phys.205. 269-275 (1996)

S. Nakabayashi：“甲醛在铂电极表面上的解离吸附动力学；一维多米诺骨牌？”

I.Yagi: "Reaction Pathway of Four Electron Oxidation of Formaldehyde on Platinum Electrode As Observed by In-Situ Optical Spectroscopy" Surf.Sci.386. 82-88 (1997)

I.Yagi：“通过原位光谱观察到的铂电极上甲醛四电子氧化的反应路径”Surf.Sci.386。

T.Nakanishi: "Construction of Semiconductor Nanoparticle Layers on Gold by Self-Assembly Technique" Jpn.J.Appl.Phys.36/6B. 4053-4056 (1997)

T.Nakanishi：“通过自组装技术在金上构建半导体纳米颗粒层”Jpn.J.Appl.Phys.36/6B。

T.Nakanishi: "Layr-by-Layr Self-assembly of Composite Films of CdS Nanoparticle and Alkanedithiol on Gold : an X-ray Photoelectron Spectroscopic Characterization" Chem.Phys.Lett.278. 233-237 (1997)

T.Nakanishi：“金上 CdS 纳米粒子和烷二硫醇复合膜的逐层自组装：X 射线光电子能谱表征”Chem.Phys.Lett.278。