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Construction of a substrate transfer system of which binding abilities can synchronize with environmental change

Construction of a substrate transfer system of which binding abilities can synchronize with environmental change
结合能力与环境变化同步的基质转移系统的构建
批准号：
14550820
负责人：
IKEDA Hiroshi
金额：
$1.92万
依托单位：
Tokyo Institute of Technology
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (C)
财政年份：
2002
资助国家：
日本
项目状态：
已结题
起止时间：
2002 至 2004
来源：
https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-14550820/
关键词：
CyclodextrinSupramoleculeRegulation of ActivityAllosteric EffectTransport through a Liquid MembraneHydrogen Bondドラッグデリバリ

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中文摘要
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英文摘要
A new efficient system for transporting saccharides through a liquid membrane has been constructed. The transport rates of saccharides were accelerated greatly by the cyclodextrin dimer 2;by contrast, the corresponding cyclodextrin monomer 1 was not effective at mediating saccharide transport. The transport rate of D-ribose through a chloroform liquid membrane was 17 times faster when the cyclodextrin dimer 2 was used as the transporter than when the cyclodextrin monomer 1 was used. Similarly the transport rate of methyl D-galactopyranoside was 16 times faster by 2 than by 1. The mechanism of transporting saccharides by this effective transporter was investigated with ^1H NMR.
期刊论文(25)
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会议论文
H.Ikeda, A.Matsuhisa, A.Ueno: "Selective Transport of Saccharides through a Liquid Membrane Using Cyclodextrin Dimer"J.Inclusion Phenom.Macrocycl.Chem.. 44. 347-350 (2002)
H.Ikeda、A.Matsuhisa、A.Ueno：“使用环糊精二聚体通过液膜选择性运输糖类”J.Inclusion Phenom.Macrocycl.Chem.. 44. 347-350 (2002)
DOI： --
发表时间：
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作者： []
通讯作者：
K.Imamura, H.Ikeda, A.Ueno: "Enhanced Binding Ability of β-Cyclodextrin Bearing Seven Hydrophobic Chains Each with a Hydrophilic End Group"Chem. Lett.. 516-517 (2002)
K.Imamura、H.Ikeda、A.Ueno：“增强了带有七个疏水链（每个链均具有亲水端基）的 β-环糊精的结合能力”Chem. 516-517 (2002)
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通讯作者：
H.Ikeda, Y.Iidaka, A.Ueno: "Remarkably Enhanced Excimer Formation of Naphthylacetate in Cation-Charged γ-Cyclodextrin"Org.Lett.. 5. 1625-1627 (2003)
H.Ikeda、Y.Iidaka、A.Ueno：“阳离子电荷 γ-环糊精中乙酸萘酯的准分子形成显着增强”Org.Lett.. 5. 1625-1627 (2003)
DOI： --
发表时间：
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通讯作者：
H.Ikeda, A.Matsuhisa, A.Ueno: "Selective Transport of Saccharides through a Liquid Membrane Using Cyclodextrin Dimer"J.Inclusion Phenom. Macrocycl.Chem.. (in press). (2003)
H.Ikeda、A.Matsuhisa、A.Ueno：“使用环糊精二聚体通过液膜选择性运输糖类”J.Inclusion Phenom。
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通讯作者：
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