molecularly imprinted Filters having Selective Recognition and Adsorption properties to Targeted Molecules of Environmental Estrogenetic nature.

分子印迹聚合物的设计方法对于具有与目标环境干扰物互补的生物大分子结合位点的过滤器来说是新颖的。因此，我们开发了一种利用相变工艺制备MIP的非共价印迹方法。所制备的印迹膜对靶分子具有超选择性识别能力，可用于选择性结合和处理大量溶质溶液的连续操作。因此，我们得出结论，由于这些优点，非常方便浓缩废水中浓度极低的环境污染物化合物。因此，MIP膜材料对这类有毒化合物的选择性吸附被认为对废液中有毒物质的去除越来越有用。在本报告的工作中，针对环境雌激素化合物和有毒化学物质，进行了印迹聚合物过滤器的研究。我们着重研究了印迹膜的识别特性，重点研究了印迹膜如何通过膜吸附实现对目标化学物质的识别功能。：(1)具有选择性识别和结合特性的双酚A印迹聚合物吸附剂。(2)靶向双酚衍生物的杂化分子印迹膜：采用(1)方法制备双酚A （BPA）印迹聚合物，采用相转化技术对聚苯乙烯（PS）、醋酸纤维素（CA）、尼龙66 （Ny）和聚砜（PSf）的多孔膜支架进行杂化；(3)制备了靶向吲哚模板的杂化分子印迹聚合物膜。采用3-吲哚乙醇（IE）与甲基丙烯酸氯酯化反应制备3-吲哚甲基丙烯酸乙酯（IEMA）。(4)采用压缩二氧化碳相分离法制备多孔印迹聚合物膜。(5)采用共价印迹技术合成了胆汁酸（BA）高识别和结合的分子印迹共聚物。(6)研究了利用模板尼龙进行高苯基丙氨酸识别的相反转分子印迹。少

Design approaches for molecular imprinting polymers are to be novel for filters having biological macromolecule binding sites complementary to the target environmental disruptors. Therefore, we have developed non-covalent imprinting method for MIP preparation, which makes use of phase inversion process. The resultant imprinting membranes showed permselective recognition to the target molecules and were very useful for selective binding and continuous operation to treat for large amounts of solute solution. Therefore, we concluded that because of these advantages, it is very convenient to concentrate environmental pollutant compounds, which are present in extreme dilute concentration in waste water. Therefore, selective adsorption of such toxic compound by MIP membrane materials is considered increasingly useful for toxic removal from waste solution. In the present report work, research effort was made aiming at using imprinted polymer filters targeted to environmental estrogenic compou … More nds and toxic chemicals. We concentrated on recognition properties of imprinted membranes and focused on how the imprinted membrane was functionalized on the recognition for their target chemicals by membrane adsorption. :(1) Bisphenol A Imprinted Polymer Adsorbents with Selective Recognition and Binding Characteristics.(2) Hybrid molecularly imprinted membranes for targeted bisphenol derivatives : Bisphenol A (BPA) imprinted polymer, which was prepared with (1) process was hybridized for porous membrane scaffolding of polystyrene (PS), cellulose acetate (CA), nylon 66 (Ny) and polysulfone (PSf) by phase inversion technique,(3) Hybrid molecularly imprinted polymer membranes targeted to indole template was presented. By using 3-indoleethylmethacrylate (IEMA) via esterification of 3-indoleethanol (IE) and methacrylic acid chloride.(4) Porous Imprinted Polymer Membranes Prepared were with Phase Separation in Compressed Carbon Dioxide.(5) Molecular imprinted copolymers, which highly recognized and bound bile acid (BA), were synthesized using covalently imprinting technique.(6) Phase inversion molecular imprinting by using template Nylons for high phenyl alanine recognition was investigated. Less