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Explorations of new optical switching phenomena in strongly correlated electron systems

强相关电子系统中新光开关现象的探索

基本信息

批准号：
16340086
负责人：
OKAMOTO Hiroshi
金额：
$ 10.43万
依托单位：
The University of Tokyo
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (B)
财政年份：
2004
资助国家：
日本
起止时间：
2004 至 2006
项目状态：
已结题

项目摘要

In this research project, we aimed to explore new kinds of photoinduced phase transitions (optical switching phenomena) in which transport, optical and magnetic properties are largely changed by lights and to clarify their physical mechanisms. The main achievements are summarized below.?Z We found an ultrafast photoinduced insulator-metal transition in a two-dimensional Mott insulator of an organic charge-transfer compound,(M_2P-F_4TCNQ). From the detailed analyses of the transient reflectivity spectra and their time dependences, we revealed that the decay time of the photoinduced metallic state is very fast, being 0.4 ps, and the metallic state is two-dimensional in nature. Such a fast decay is considered characteristic of two-dimensional correlated electron systems.?Z We found an ultrafast photoinduced insulator-metal transition in a one-dimensional Mott insulator of an organic charge-transfer compound,(BEDTTTF-F_2TCNQ). The important feature of this transition is that a metallic behavior was observed even for a very weak excitation photon density (<0.003 photon/site). We concluded that such a formation of a metallic state by a weak excitation is attributable to the spin-charge separation characteristic of 1D correlated electron systems.?Z We found an ultrafast photoinduced charge density wave (CDW)-Mott Hubbard transition in a typical transition metal compound with a one-dimensional correlated electron system, an iodine-bridged platinum compound. Werevealed that the efficiency of the transition is very high (ca. 70 Pt sites per photon) and that a CDW to metal transition occurs by a strong excitation. Namely, photoinduced phase transitions among three phases (CDW, Mott-Hubbard, metal) are possible in this compound.Thus, in this project, we have succeeded in exploring new photoinduced phase transitions and achieved the clarifications of their physical mechanisms.

在本研究项目中，我们旨在探索光在很大程度上改变输运、光学和磁性质的新型光诱导相变（光开关现象），并阐明其物理机制。主要成就总结如下。我们在有机电荷转移化合物（m_2p - f_4 - tcnq）的二维Mott绝缘体中发现了超快的光致绝缘体-金属跃迁。通过对瞬态反射光谱及其时间依赖性的详细分析，我们发现光诱导金属态的衰减时间非常快，为0.4 ps，并且金属态本质上是二维的。这种快速衰变被认为是二维相关电子系统的特征。我们在有机电荷转移化合物（BEDTTTF-F_2TCNQ）的一维Mott绝缘体中发现了超快的光致绝缘体-金属跃迁。这种转变的重要特征是，即使在非常弱的激发光子密度（<0.003光子/位）下也观察到金属行为。我们得出结论，弱激发下金属态的形成是由于一维相关电子系统的自旋-电荷分离特性。我们在一个具有一维相关电子系统的典型过渡金属化合物，碘桥铂化合物中发现了超快光致电荷密度波(CDW)-Mott Hubbard跃迁。我们发现，转换效率非常高（每光子约70 Pt位），并且CDW到金属的转换发生在强激发下。也就是说，光诱导相变之间的三个阶段（CDW, Mott-Hubbard，金属）是可能的在该化合物。因此，在这个项目中，我们成功地探索了新的光诱导相变，并澄清了它们的物理机制。

项目成果

期刊论文数量（65）

专著数量（0）

科研奖励数量（0）

会议论文数量（0）

专利数量（0）

Tuning of electronic structures of quasi one-dimensioal iodide-bridged dinuclear platinum mixed-valence complexes

准一维碘桥双核铂混价配合物电子结构的调控

DOI：
发表时间：
2006
期刊：
Coordination Chemistry Reviews 250
影响因子：
0
作者：
M.Yamashita;H.Okamoto;et al.
通讯作者：
et al.

Thermochromism in an organic crystal based on the coexistence of o- and n-dimers

基于 o- 和 n-二聚体共存的有机晶体中的热致变色现象

DOI：
发表时间：
2008
期刊：
Nature Materials 1
影响因子：
0
作者：
Y. Morita;et al.
通讯作者：
et al.

Thermochromism in an organic crystal based on the coexistence of 〓 and π-dimers

基于〓和π-二聚体共存的有机晶体中的热致变色

DOI：
发表时间：
2008
期刊：
Nature Materials 7
影响因子：
0
作者：
Y. Morita;et. al.
通讯作者：
et. al.

Optical control of the magnetic anisotropy of ferromagnetic bilayered manganites.

DOI：
10.1103/physrevlett.98.017402
发表时间：
2007-01
期刊：
Physical review letters
影响因子：
8.6
作者：
S. Tomimoto;M. Matsubara;T. Ogasawara;H. Okamoto;T. Kimura;Y. Tokura
通讯作者：
S. Tomimoto;M. Matsubara;T. Ogasawara;H. Okamoto;T. Kimura;Y. Tokura

Photoinduced switching between charge and orbital ordered insulator and ferromagnetic metal in perovskite manganites

DOI：
10.1103/physrevb.77.094410
发表时间：
2008-03
期刊：
Physical Review B
影响因子：
3.7
作者：
M. Matsubara;Y. Okimoto;T. Ogasawara;S. Iwai;Y. Tomioka;H. Okamoto;Y. Tokura
通讯作者：
M. Matsubara;Y. Okimoto;T. Ogasawara;S. Iwai;Y. Tomioka;H. Okamoto;Y. Tokura