The development and physical properties of two-dimensional Li+ ionic-conductor used rotator phases as matrix
The development and physical properties of two-dimensional Li+ ionic-conductor used rotator phases as matrix
批准号:
19750011
负责人:
TANAKA Susumu
金额:
$2.44万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2008
中文摘要
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英文摘要
炭素数4,6,8,10,12の塩化n-アルキルアンモニウムが融点直下で形成する二次元的なイオン伝導パスをもったrotator 相へ、ごく少量のLiCl を添加すると、アルキル鎖の短い塩化n-アルキルアンモニウムほど電気伝導度が増加しやすく、LiCl 無添加物と比較して最大約15 倍まで増加することを確認した。また、固体NMR スペクトルからは、リチウムイオンがアルキルアンモニウムイオンの親水基末端付近にある2 種の異なったサイトに位置することを明らかにした。
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依托单位:
海外基金