Exploitation of Mechanostress-Induced Molecular Aggregation and Its Application to Functional Molecular Devices

探索了利用机械应力作为外部刺激来控制衣针状钯、铂配合物的流动性和分子重排的清洁和远程方法，以创造一种新的功能材料。环状双核钯络合物的分子组装可以通过超声作用时间、溶剂以及其结构异构体的加入等反应条件来控制。此外，还发现相应的铂配合物表现出超声诱导的发射增强现象。

Clean and remote methods for controlling fluidity and molecular rearrangement of clothes-pin shaped palladium and platinum complexes by mechanostress as an external stimuli was explored in order to create a new functional materials. Molecular assembly of cyclic dinuclear palladium complex can be controlled by reaction conditions such as sonication time, solvent, and addition of its structural isomer. Furthermore, the corresponding platinum complexes were found to show sonication-induced emission enhancement phenomenon.