Living radical polymerization of fluorine vinyl monomer using long-term radicals in solid state and application of fuel cell membrane.

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For synthesis of polymer electrolyte membrane (PEM) that can be applied to fuel cells for mobile electricity in vehicles, as well as a domestic co-generation system, radiation-induced graft polymerization is a convenient method to introduce directly graft chains with proton conductivity into fluorine polymer. A superior durable PEM which introduced fluorine vinyl monomer into polymer films can be obtained by using both long-term radicals by irradiation for graft polymerization and stable radicals for living radical polymerization.