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A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion

A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion
Ce(IV)介导的氟离子活化有机硅化合物自由基产生的研究
批准号：
20590003
负责人：
UCHIYAMA Masahiko
金额：
$3.0万
依托单位：
Kanazawa University
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (C)
财政年份：
2008
资助国家：
日本
项目状态：
已结题
起止时间：
2008 至 2010
来源：
https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-20590003/
关键词：
ラジカルセリウム一電子酸化フッ素アニオン有機ケイ素化合物

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中文摘要
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英文摘要
Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion was studied. Although the generation of radical by this method has not been obsereved to date, we observed the C-C bond formation reactions with catalytic amount of Ce(IV) or Ce(III) in aqueous media in the course of this study.
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Development of functional non-naturally occurring protein which can be modified site-specifically according with "artificial gene code"
  • 批准号：
    19800013
  • 项目类别：
    Grant-in-Aid for Young Scientists (Start-up)
  • 资助金额：
    $1.99万
  • 财政年份：
    2007
  • 负责人：
    UCHIYAMA Masahiko
  • 依托单位：
    Tokyo Institute of Technology
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