A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion
A study on Ce (IV)-mediated radical generation from organosilicon compounds activated by fluoride ion
Ce(IV)介导的氟离子活化有机硅化合物自由基产生的研究
批准号：
20590003
负责人：
UCHIYAMA Masahiko
金额：
$3.0万
依托单位：
依托单位国家：
日本
项目类别：
Grant-in-Aid for Scientific Research (C)
财政年份：
2008
资助国家：
日本
项目状态：
已结题
起止时间：
2008 至 2010
中文摘要
翻译
研究了氟离子活化有机硅化合物中Ce（IV）介导的自由基生成。虽然迄今为止还没有观察到这种方法生成自由基的过程，但在本研究过程中，我们在水介质中观察到催化量为Ce（IV）或Ce（III）的C-C键形成反应。
英文摘要
Ce(IV)-mediated radical generation from organosilicon compounds activated by fluoride ion was studied. Although the generation of radical by this method has not been obsereved to date, we observed the C-C bond formation reactions with catalytic amount of Ce(IV) or Ce(III) in aqueous media in the course of this study.
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会议论文
Development of functional non-naturally occurring protein which can be modified site-specifically according with "artificial gene code"
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批准号：19800013
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项目类别：Grant-in-Aid for Young Scientists (Start-up)
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资助金额：$1.99万
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财政年份：2007
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负责人：UCHIYAMA Masahiko
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依托单位：
海外基金
