Development of dye-sensitized solar cells with over 1 V open circuit voltage
Development of dye-sensitized solar cells with over 1 V open circuit voltage
批准号:
20750156
负责人:
YAMAGUCHI Takeshi
金额:
$1.58万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (B)
财政年份:
2008
资助国家:
日本
项目状态:
已结题
起止时间:
2008 至 2009
中文摘要
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英文摘要
In this study, for the investigation of higher voltage DSCs, we adopted Br^-/Br_3^- as a redox pair. Br^-/Br_3^- has more positive redox level than I^-/I_3^- and its combination with TiO2 is considered to enable high voltage DSCs. We selected tris-(4, 4'- dicarboxylate-2, 2'-bipyridine) ruthenium(II) ((dcbpy)_3Ru) as a dye showing proper HOMO-LUMO level for Br^-/Br_3^- redox level and TiO_2 conduction band. Furthermore, we synthesized some (dcbpy)_2(R2bpy)Ru complexes as the dye having proper HOMOLUMO level for Br^-/Br_3^- redox level. We investigated DSC performances sensitized by these dye complexes. By using Br-/Br3- electrolyte, (dcbpy)_2(bpy)Ru-sensitized cell showed 3.5% efficiency with high Voc = 1.01 V.
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Efficiency Improvement of Dye-Sensitized Solar Cells Using Series-Connected Tandem Structure
利用串联结构提高染料敏化太阳能电池的效率
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[Takeshi Yamaguchi, Kenichi Motomura, Hironori Arakawa]
通讯作者:
Hironori Arakawa
各種置換基を有するトリス(ビピリジル)ルテニウム錯体を用いた色素増感太陽電池の高電圧化
使用具有各种取代基的三(联吡啶)钌络合物提高染料敏化太阳能电池的电压
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[山口岳志, 羽野修平, 荒川裕則]
通讯作者:
荒川裕則
Significant photovoltage improvement of DSCs with (dcbpy)_3Ru sensitizer and Br^-Br_3^- redox electrolyte
使用 (dcbpy)_3Ru 敏化剂和 Br^-Br_3^- 氧化还原电解质显着提高 DSC 的光电压
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[山口岳志, 他5名]
通讯作者:
他5名
各種置換基を有するトリス(ビピリジル)ルテニウム錯体と臭素系電解液を用いた色素増感太陽電池の高電圧化
使用具有各种取代基的三(联吡啶)钌配合物和溴基电解质提高染料敏化太阳能电池的电压
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[山口岳志, 羽野修平, 荒川裕則]
通讯作者:
荒川裕則
臭素系電解液に適合した増感色(dcbpy)2 Ru(R2bpy)を用いた色素増感太陽電池の高電圧化
使用与溴基电解质兼容的敏化颜色 (dcbpy)2 Ru (R2bpy) 进行染料敏化太阳能电池的高压开发
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[山口岳志, 羽野修平, 荒川裕則, 羽野修平・山口岳志・荒川裕則]
通讯作者:
羽野修平・山口岳志・荒川裕則
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