Development of Novel Fluorinated Polymeric Nanoparticles According to the Environmental Changes and Design of Their Composite Functionalized Life Materials

根据环境变化开发新型含氟聚合物纳米粒子及其复合功能化生命材料的设计

• 批准号: 21550179
• 负责人: SAWADA Hideo
• 金额: $ 3.16万
• 依托单位: Hirosaki University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (C)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2011
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21550179/
• 关键词: 含フッ素オリゴマー; ナノコンポジット; シリカナノ粒子; 表面処理; 防汚・親水; 超親水; 超撥油性; 抗菌活性; 超撥水性; 超親水性; ハイドロガーネット; 密着性; 酸化亜鉛

A variety of fluorinated oligomers/silica nanocomposites, which are useful for new fluorinated polymeric nanoparticle surface modifiers, have been prepared in this study, and their dispersibility and thermal stability have been also studied in detail. Furthermore, based on these results, we have succeeded in the elucidation of the oleophobic-hydrophilic characteristics through the flip-flop motion according to the environmental change on the modified surface treated with these fluorinated polymeric nanoparticles.

在这项研究中已经准备好了多种氟化寡聚物/二氧化硅纳米复合材料，可用于新的氟化聚合物纳米颗粒表面修饰剂，并且还详细研究了它们的分散性和热稳定性。此外，根据这些结果，根据这些氟化聚合物纳米颗粒处理的改性表面的环境变化，我们通过触发器运动成功地通过触发器运动阐明了含嗜噬恐惧症的养育性特征。

项目成果

Controlled Immobilization of Palladium Nanoparticles in Two Different Fluorinated Polymeric Aggregate Cores and Their Application in Catalysis

钯纳米粒子在两种不同氟化聚合物聚集体核中的受控固定化及其在催化中的应用

• DOI: 10.1007/s00396-011-2567-9
• 发表时间: 2011
• 期刊: Colloid Polym Sci
• 影响因子: 2.4
• 作者: T. Kijima;I. Javakhishvili;K. Jankova;S. Hvilsted;S. Kodama;M. Sugiya;and H. Sawada
• 通讯作者: and H. Sawada

Preparation of Novel Fluoroalkyl End-capped Trimethoxyvinylsilane Oligomeric Nanoparticles-Encapsulated Binaphthol : Encapsulated Binaphthol Possessing a Thermally Stable Characteristic Even at 800℃

新型氟烷基封端三甲氧基乙烯基硅烷低聚物纳米粒子-包封联萘酚的制备：包封联萘酚即使在800℃也具有热稳定特性

• 发表时间: 2010
• 期刊: Bull. Chem. Soc. Jpn
• 作者: H. Sawada;Y. Matsuki;Y. Goto;S. Kodama;M. Sugiya;and Y. Nishiyama
• 通讯作者: and Y. Nishiyama

Fluoroalkyl End-capped Oligomers Possessing Nonflammable and Flammable Characteristics in Silica Gel Matrices (Invited lecture)

硅胶基质中具有不燃和易燃特性的氟烷基封端低聚物（特邀报告）

• 发表时间: 2010
• 作者: 近藤行成;松本晶子;佐藤和郎;近藤行成;H.Sawada
• 通讯作者: H.Sawada

フルオロアルキル基含有ビニルトリメトキシシランオリゴマー/酸化亜鉛ナノコンポジットの調製と表面改質への応用

含氟烷基乙烯基三甲氧基硅烷低聚物/氧化锌纳米复合材料的制备及其表面改性应用

• 发表时间: 2009
• 作者: 近藤行成;松本晶子;佐藤和郎;近藤行成;H.Sawada;櫻井芳昭;澤田英夫;Yukishige Kondo;佐々木高広;Yukishige Kondo;岡田良隆;平山優太郎
• 通讯作者: 平山優太郎

Preparation and properties of novel cross-linked fluoroalkyl end-capped cooligomeric nanoparticles possessing double decker-type aromatic silsesquioxane segments as core units

• DOI: 10.1007/s00396-011-2474-0
• 发表时间: 2011-06
• 期刊: Colloid and Polymer Science
• 影响因子: 2.4
• 作者: Yuki Goto;Kazuhiro Yoshida;H. Sawada