Synthesis and Application of Planar Chiral Heterocycles

为了探索平面手性杂环化合物的化学性质，我们实现了以下几个方面的工作：1）平面手性九元二烯丙基酰胺的立体选择性多峰转化; 2）PtCl 2对平面手性九元二烯丙基酰胺的独特官能团转化（2，4，6-三甲基吡啶）配合物; 3）平面手性九元二烯丙基酰胺的对映选择性合成; 4）平面手性（E）-5-环壬烯-1-酮及其烯醇化物的合成与应用; 5）平面手性[7]邻环芳的合成与应用

To explore the chemistry of planar chiral heterocycles, we achieved the following: 1) stereoselective multimodal transformations of planar chiral nine-membered diallylic amides; 2) a unique functional group transformation of planar chiral nine-membered diallylic amides by using PtCl2 (2,4,6-trimethylpyridine) complexes; 3) enantioselective synthesis of planar chiral nine-membered diallylic amides; 4) synthesis and application of planar chiral (E)-5-cyclononen-1-one and its enolate; and 5) synthesis and application of planar chiral [7]orthocyclophanes