Synthesis and application of porous crosslinked polymers and carbons

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Monolithic activated carbon electrodes with high specific surface area have been prepared through carbonization and activation of poly(divinylbenzene), which were prepared by controlled/living radical polymerization. These electrodes show relatively high specific capacitance and good cycle and rate performances. In addition, carbonization of macroporous melamine-formaldehyde resins has been investigated for the purpose of obtaining nitrogen-doped porous carbons. By introducing resorcinol in the preparation of resins, it has been demonstrated that nitrogen-doped carbons with retained macroporous structure have been obtained.