Concerto Redox Properties for Inorganic-Organic Hybrid Nanoclusters

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New inorganic-organic hybrid Nanoclusters were synthesized by using Zwitter ionic ligands and various metal ions. The synthesized clusters were clarified about their structures in the solid and in solution, the electrochemical properties, and the spectroscopy characters. The interactions between ligands and metals for multi-electronic redox system of electronic and structural characters were examined based on the obtained results. The electronic state and the analyses of their structures were carried out by also using the computational calculations. The new Zwitter ionic ligands that showed more complex multi electron redox system were developed. The evaluation of their functionality as the Nano-material was tried from these results. Thesis submission was done for a part of the result of obtaining, and the result was made public.