様々な金属を用いたメソポーラスMetal Phosphonate物質の新合成

利用多种金属新合成介孔金属膦酸盐材料

• 批准号: 17F17047
• 负责人: 山内 悠輔
• 金额: $ 1.47万
• 依托单位: National Institute for Materials Science
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for JSPS Fellows
• 财政年份: 2017
• 资助国家: 日本
• 起止时间: 2017-04-26 至 2018-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-17F17047/
• 关键词: Mesoporous materials

In some cases, the obtained materials showed less-ordered/dis-ordered porous structure with the amorphous pore walls and less surface area, due to the lack of intermolecular interaction between aliphatic chains of phosphonic acid precursors. In this year, we designed new phosphonic acid sources with aromatic rings, and could increase effective interaction to realize highly mesostructural ordering and crystalized walls. Especially, we considered the interaction between surfactants, phosphonic acids, and metal precursors. We used cetyltrimethylammonium bromide (CTAB), oligomeric surfactants (C16EO10, C16EO20), and triblock copolymers (EO80PO30EO80, EO106PO70EO106, and EO20PO70EO20) as structure-directing agents. To remove the templates, as-prepared mesostructured samples were washed with solvents. After that, we carefully characterized the obtained mesoporous samples and we could find out the optimal synthetic conditions.

在某些情况下，由于膦酸前体的脂肪链之间缺乏分子间相互作用，所获得的材料显示出具有无定形孔壁和较小表面积的较不有序/无序的多孔结构。今年，我们设计了新的具有芳香环的膦酸源，并且可以增加有效的相互作用以实现高度介观结构有序和结晶壁。特别地，我们考虑了表面活性剂、膦酸和金属前体之间的相互作用。我们使用十六烷基三甲基溴化铵（CTAB），低聚表面活性剂（C16 EO 10，C16 EO 20），和三嵌段共聚物（EO 80 PO 30 EO 80，EO 106 PO 70 EO 106，和EO 20 PO 70 EO 20）作为结构导向剂。为了除去模板，用溶剂洗涤制备的介观结构样品。在此之后，我们仔细表征所获得的介孔样品，我们可以找到最佳的合成条件。

项目成果

Mesoporous Semimetallic Conductors: Structural and Electronic Properties of Cobalt Phosphide Systems

介孔半金属导体：磷化钴体系的结构和电子性能

• DOI: 10.1002/ange.201707878
• 发表时间: 2017
• 期刊: Angewandte Chemie International Edition
• 作者: Malay Pramanik;Satoshi Tominaka;Zhong-Li Wang;Toshiaki Takei;Yusuke Yamauchi
• 通讯作者: Yusuke Yamauchi