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THE CHEMISTRY OF NATURAL PRODUCTS

THE CHEMISTRY OF NATURAL PRODUCTS
天然产物的化学原理
批准号：
3268040
负责人：
GEORGE H BUCHI
金额：
$28.15万
依托单位：
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
依托单位国家：
美国
项目类别：
财政年份：
1977
资助国家：
美国
项目状态：
已结题
起止时间：
1977-04-01 至 1987-03-31
来源：
https://reporter.nih.gov/project-details/3268040
关键词：
DNA chemical structure chemical synthesis drug design /synthesis /production genetic transcription mycotoxins saxitoxin tetrodotoxin vinblastine vincristine

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中文摘要
翻译
以一溴代溴和二溴代溴合成海产品
英文摘要
The marine products monobromo and dibromphakellin will be synthesized by a biogenetically patterned route. In a related study a synthesis of the paralytic shellfish poison saxitoxin is investigated. Mirestrol a plant estrogen not belonging to the steriods is being synthesized. Lysergic acid and some related compounds are structural units of several drugs. A biogenetically patterned synthesis of lysergic acid and related ergolines is being developed. Attempts are being made to convert bisnaphthoquinones to intramolecular aldol products containing the basic ring structures of the naphthocyclinone antibiotics. A speculative scheme for the biogenesis of the thiaspirane alkaloids is being tested experimentally. A new antibiotic produced by Aspergillus parasiticus will be synthesized.
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