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PERICYCLIC REACTIONS FOR ORGANIC SYNTHESIS

PERICYCLIC REACTIONS FOR ORGANIC SYNTHESIS
有机合成的周环反应
批准号：
3275567
负责人：
RICK L DANHEISER
金额：
$15.41万
依托单位：
MASSACHUSETTS INSTITUTE OF TECHNOLOGY
依托单位国家：
美国
项目类别：
财政年份：
1980
资助国家：
美国
项目状态：
已结题
起止时间：
1980-07-01 至 1990-06-30
来源：
https://reporter.nih.gov/project-details/3275567
关键词：
anthracyclines antifungal antibiotics antiviral agents carbonyl group chemical synthesis cyclic compound cyclization cyclopropanes drug design /synthesis /production ketene ketones phenols sesquiterpenes stereochemistry

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中文摘要
翻译
本文重点介绍了周环反应在新材料中的应用
英文摘要
This proposal focuses on the application of pericyclic reactions in new methodology for the synthesis of several important classes of organic compounds. General, stereocontrolled routes to functionalized cyclopropane derivatives will be developed based on the chemistry of cyclopropylboranes. Anion-accelered [1,3] sigmatropic rearrangements will be employed in stereocontrolled annulation approaches to five-membered carbocyclic compounds. A regiocontrolled annulation route to highly substituted aromatic compounds will be developed and applied to the total synthesis of the biologically important natural products bhogatin, ascochlorin, cristatin, barbatusol, and mycophenolic acid
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Pericyclic Reactions for Organic Synthesis
PERICYCLIC REACTIONS FOR ORGANIC SYNTHESIS
Pericyclic Reactions for Organic Synthesis
PERICYCLIC REACTIONS FOR ORGANIC SYNTHESIS
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