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ALKALOID SYNTHESIS VIA 2-ALKENYL-1,2-DIHYDROPYRIDINES

ALKALOID SYNTHESIS VIA 2-ALKENYL-1,2-DIHYDROPYRIDINES
通过 2-烯基-1,2-二氢吡啶合成生物碱
批准号：
3277913
负责人：
DANIEL L COMINS
金额：
$7.4万
依托单位：
NORTH CAROLINA STATE UNIVERSITY RALEIGH
依托单位国家：
美国
项目类别：
财政年份：
1989
资助国家：
美国
项目状态：
已结题
起止时间：
1989-01-01 至 1991-03-31
来源：
https://reporter.nih.gov/project-details/3277913
关键词：
Diels Alder reaction diene drug design /synthesis /production indoles

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中文摘要
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英文摘要
The objective of this proposal is to continue our studies on developing practical methods for the synthesis of novel bridged polycyclic compounds and biologically active alkaloids via intramolecular cycloaddition reactions of 1-acyldihydropyridines. Specific aims are (1) to complete the total synthesis of (plus/minus)-gephyrotoxin by the INOC or IMDA routes (2) to investigate approaches to the asymmetric synthesis of (+)- gephyrotoxin, and (3) to study an approach to the synthesis of the Lycopodium alkaloid, (+)-luciduline.
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