Illuminating hidden processes in emissive lanthanoid complexes

照亮发射性镧系元​​素配合物中的隐藏过程

• 批准号: DP170101895
• 负责人: A/Prof Evan Moore
• 金额: $ 33.01万
• 依托单位: The University of Queensland
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2017
• 资助国家: 澳大利亚
• 起止时间: 2017-03-31 至 2021-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP170101895
• 关键词: Illuminating; hidden; processes; emissive; lanthanoid

This project aims to understand the antenna effect used to sensitise lanthanoid luminescence. Despite their use in modern high-tech applications, from optical fibre amplifiers (telecommunications) to luminescent probes and sensors (biological imaging), understanding is largely based on speculation or generalised 'rules-of-thumb', severely limiting progress in the field. This project will research these processes, using chemical synthesis, theory and spectroscopic techniques. This is expected to lead to new emissive lanthanoid-based compounds using 'a priori' approaches, with better performance than current gold standards and references. Intellectual property created will lead to new commercial products, and to creation of new Australian based spin-off/start-up companies.

该项目旨在了解用于敏感镧系发光的天线效应。尽管它们在现代高科技应用中得到了应用，从光纤放大器（电信）到发光探针和传感器（生物成像），但对它们的理解很大程度上是基于猜测或广义的“经验法则”，严重限制了该领域的进展。本项目将利用化学合成、理论和光谱技术研究这些过程。预计这将导致使用“先验”方法的新型发光镧系化合物，其性能优于当前的金标准和参考文献。所创造的知识产权将导致新的商业产品，并创造新的澳大利亚衍生/创业公司。