G8-2012 Ink-jet printed single-crystal organic photovoltaics (IPSOP)

G8-2012 喷墨印刷单晶有机光伏电池（IPSOP）

• 批准号: EP/K025651/1
• 负责人: Henning Sirringhaus
• 金额: $ 52.85万
• 依托单位: University of Cambridge
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2013
• 资助国家: 英国
• 起止时间: 2013 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FK025651%2F1
• 关键词: G8; 2012; Ink; jet; printed

87% of global energy production in 2010 was derived from unsustainable fossil fuels and as energy consumption grows, we urgently need to move towards renewable, clean energy sources to ensure national and international energy security. Only ~36 kWh/day/person could realistically be generated by non-solar renewables, falling short of the global target for energy requirements of 80 kWh/day/person. Therefore, without relying on nuclear energy, we must ensure that solar energy fills the gap. To meet demand, we require as many on- and off-grid photovoltaic (PV) technologies as possible and development of sustainable, low-energy and material-light technologies should be prioritized. In this context, ink-jet printing organic semiconductors is highly attractive.Our project aims to use similar processing techniques to demonstrate a dramatic step change in PV efficiency tomatch that of transistors. Such a step change requires a global consortium such as ours, including world-leading chemists (USA), physicists/engineers (UK) and material scientists (Japan) as well as knowledge of market requirements (Organic PV company). We aim to tackle the whole PV cycle, from materials to exploitation. In particular concentrating on (i) sustainable approaches to organic semiconductor synthesis, potentially allowing organic PVs to be made out of bio waste such as corn stover,(ii) creating highly ordered PVs using novel adapted ink-jet printing and vapor-phase deposition (and comparing the two techniques)(iii) quantitatively characterising the single crystal structure, physics and morphology(iv) characterizing the finished PVs, including stability and lifetime.Constant feedback between the groups will be used to optimize the materials and processing techniques to develop revolutionary >10% efficient sustainable PVs.

2010年，全球能源产量的87%来自不可持续的化石燃料，随着能源消费的增长，我们迫切需要转向可再生清洁能源，以确保国家和国际能源安全。非太阳能可再生能源实际上只能产生约36千瓦时/天/人，低于80千瓦时/天/人的全球能源需求目标。因此，在不依赖核能的情况下，我们必须确保太阳能填补差距。为了满足需求，我们需要尽可能多的并网和离网光伏（PV）技术，并应优先开发可持续、低能耗和材料轻技术。在这种情况下，喷墨打印有机半导体是非常有吸引力的。我们的项目旨在使用类似的处理技术，以证明一个戏剧性的阶跃变化的光伏效率，以配合晶体管。这样的一个阶段性变化需要像我们这样的全球联盟，包括世界领先的化学家（美国），物理学家/工程师（英国）和材料科学家（日本）以及市场需求的知识（有机光伏公司）。我们的目标是解决整个光伏周期，从材料到开发。特别是集中在（i）有机半导体合成的可持续方法，潜在地允许有机PV从生物废物如玉米秸秆中制成，（ii）使用新的适应性喷墨印刷和气相沉积来创建高度有序的PV（和比较两种技术）（iii）定量表征单晶结构、物理和形态（iv）表征成品PV，包括稳定性和使用寿命。团队之间的持续反馈将用于优化材料和加工技术，以开发效率>10%的革命性可持续PV。

项目成果

The entangled triplet pair state in acene and heteroacene materials

并苯和杂并苯材料中的纠缠三重态对态

• DOI: 10.17863/cam.11233
• 发表时间: 2017
• 作者: Yong C

All-Inkjet-Printed, All-Air-Processed Solar Cells

• DOI: 10.1002/aenm.201400432
• 发表时间: 2014-10-07
• 期刊: ADVANCED ENERGY MATERIALS
• 影响因子: 27.8
• 作者: Jung, Sungjune;Sou, Antony;Sirringhaus, Henning
• 通讯作者: Sirringhaus, Henning

The entangled triplet pair state in acene and heteroacene materials.

• DOI: 10.1038/ncomms15953
• 发表时间: 2017-07-12
• 期刊: Nature communications
• 影响因子: 16.6
• 作者: Yong CK;Musser AJ;Bayliss SL;Lukman S;Tamura H;Bubnova O;Hallani RK;Meneau A;Resel R;Maruyama M;Hotta S;Herz LM;Beljonne D;Anthony JE;Clark J;Sirringhaus H
• 通讯作者: Sirringhaus H

Stability investigations of inverted organic solar cells with a sol-gel processed ZnSrO or ZnBaO electron extraction layer

具有溶胶-凝胶处理的 ZnSrO 或 ZnBaO 电子提取层的倒置有机太阳能电池的稳定性研究

• DOI: 10.1117/12.2023247
• 发表时间: 2013
• 作者: Pachoumi O

Improved Performance of ZnO/Polymer Hybrid Photovoltaic Devices by Combining Metal Oxide Doping and Interfacial Modification

• DOI: 10.1021/jp506266f
• 发表时间: 2014-08
• 期刊: Journal of Physical Chemistry C
• 影响因子: 3.7
• 作者: O. Pachoumi;A. Bakulin;A. Sadhanala;H. Sirringhaus;R. Friend;Y. Vaynzof