Sustainable polymers

可持续聚合物

• 批准号: EP/L017393/1
• 负责人: James Clark
• 金额: $ 373.51万
• 依托单位: University of York
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2014
• 资助国家: 英国
• 起止时间: 2014 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FL017393%2F1
• 关键词: Sustainable; polymers

Over 90% of bulk polymers with a production volume of greater than 150 million tonnes per annum are sourced from crude oil. Within the UK, the polymers industry directly employs 286,000 people and has annual sales of £18.1 billion which accounts for 2.1% of UK GDP. It produces around 2.5 million tonnes of polymer every year and is achieving an annual growth of 2.5%. The UK is in the top 5 polymer producers in the EU and its exports are worth £4.6 billion to the UK economy.These polymers are ubiquitous in everyday life and have many applications including: medical, transport, electrical, construction and packaging; the latter accounting for over a third of all polymers produced. This dependence on petrochemicals for polymer production has environmental and economic risks and will, ultimately, become unsustainable as supplies of crude oil become exhausted. Therefore, there are good reasons to develop new processes for polymer production using renewable resources and for the UK, such resources must not compete with food production. Carbon dioxide is a particularly promising renewable resource, especially the use of waste carbon dioxide from sources such as power stations, chemical plants, cement and metal works.The overall aim of this project is to develop the chemistry and engineering required to transform waste biomass and carbon dioxide into commodity polymers (2011 global production 280 million metric tonnes), specifically: polyalkanes, polyethers, polyesters, polycarbonates and polyurethanes. The key reaction pathway is from biomass to alkenes (polymerizable to polyalkanes) to epoxides which can be polymerized to polyethers or copolymerized to produce polyesters or polycarbonates. These can be further reacted to produce polyurethanes suitable for applications in furniture, insulation and adhesives. For this to be sustainable, the alkene and other reactants must also be sustainably sourced and we will investigate the use of terpenes, sugar derivatives and unsaturated acid derivatives obtained from agricultural and forestry waste. For example, during the 2011-2012 growing season, the EU processed 1.9 million metric tonnes of citrus producing approximately 950,000 metric tonnes of waste. After removal of water this left 190,000 metric tonnes of residue from which about 14,000 metric tonnes of limonene could be isolated for use as a polymer feedstock. In addition to carrying out the required chemical research, the engineering necessary to scale up the syntheses to pilot plant and production scale will be carried out.The chemical and mechanical processes associated with isolating materials from biomass and converting them into polymers will inevitably require energy and other chemicals, the production of which will generate carbon dioxide. Therefore, lifecycle analysis will be used to determine all of the carbon dioxide emissions associated with polymer production from both petrochemical and biomass sources. Comparison of the data will provide a quantitative understanding of how much better the sustainable route is than the petrochemical route and will illustrate which aspects of the synthesis are responsible for most of the carbon dioxide emissions. This, combined with energy usage and cost data will allow the project team to concentrate their efforts on minimising these emissions through for example the use of microwave heating rather than conventional heating and the use of alternative solvents such as supercritical carbon dioxide.In summary, polymers are ubiquitous in everyday life and the polymer industry is a major UK employer. Their scale of production and range of applications means that they are a high priority target to switch from fossil to sustainable sourcing. Successful completion of this project will protect UK jobs, protect the UK supply of these essential materials and provide income through license agreements with overseas manufacturers.

年产量超过1.5亿吨的本体聚合物中，90%以上来自原油。在英国，聚合物行业直接雇佣了286，000人，年销售额为181亿英镑，占英国GDP的2.1%。它每年生产约250万吨聚合物，年增长率为2.5%。英国是欧盟五大聚合物生产国之一，其出口额为46亿英镑。这些聚合物在日常生活中无处不在，并有许多应用，包括：医疗，运输，电气，建筑和包装;后者占所有聚合物产量的三分之一以上。聚合物生产对石化产品的依赖具有环境和经济风险，并且最终将随着原油供应的耗尽而变得不可持续。因此，有充分的理由开发新的工艺，用于聚合物生产使用可再生资源和英国，这些资源必须不与食品生产竞争。二氧化碳是一种特别有前途的可再生资源，特别是利用发电站、化工厂、水泥和金属厂等来源的废二氧化碳。本项目的总体目标是开发将废生物质和二氧化碳转化为商品聚合物所需的化学和工程技术（2011年全球产量2.8亿公吨），具体包括：聚烷烃、聚醚、聚酯、聚碳酸酯和聚氨酯。关键的反应途径是从生物质到烯烃（可聚合成聚烷烃）再到环氧化物，环氧化物可以聚合成聚醚或共聚以产生聚酯或聚碳酸酯。这些可以进一步反应以生产适用于家具、绝缘和粘合剂的聚氨酯。为了实现可持续发展，烯烃和其他反应物也必须以可持续的方式获得，我们将研究从农业和林业废物中获得的萜烯，糖衍生物和不饱和酸衍生物的使用。例如，在2011-2012年生长季节，欧盟加工了190万公吨柑橘，产生了约95万公吨废物。除去水后，留下190，000公吨残余物，从中可以分离出约14，000公吨柠檬烯用作聚合物原料。除了进行必要的化学研究外，还将进行必要的工程设计，以将合成扩大到试验工厂和生产规模。与从生物质中分离材料并将其转化为聚合物相关的化学和机械过程不可避免地需要能源和其他化学品，这些化学品的生产将产生二氧化碳。因此，生命周期分析将用于确定与石化和生物质来源的聚合物生产相关的所有二氧化碳排放量。数据的比较将提供一个定量的了解有多少更好的可持续的路线比石化路线，并将说明哪些方面的合成是负责大部分的二氧化碳排放。结合能源使用和成本数据，项目团队可以集中精力通过使用微波加热而不是传统加热以及使用超临界二氧化碳等替代溶剂来最大限度地减少这些排放。总之，聚合物在日常生活中无处不在，聚合物行业是英国的主要雇主。它们的生产规模和应用范围意味着它们是从化石转向可持续采购的高度优先目标。该项目的成功完成将保护英国的就业机会，保护英国对这些基本材料的供应，并通过与海外制造商的许可协议提供收入。

项目成果

Rapid Ring-Opening Metathesis Polymerization of Monomers Obtained from Biomass-Derived Furfuryl Amines and Maleic Anhydride.

• DOI: 10.1002/cssc.201900748
• 发表时间: 2019-06
• 期刊: ChemSusChem
• 影响因子: 8.4
• 作者: A. Blanpain;J. Clark;T. Farmer;Yuanlong Guo;Ian D. V. Ingram;John E Kendrick;S. Lawrenson;M. North;George F. Rodgers;A. Whitwood

Linear estimators of biomass yield maps for improved biomass supply chain optimisation

• DOI: 10.1016/j.apenergy.2019.113526
• 发表时间: 2019-11
• 期刊: Applied Energy
• 影响因子: 11.2
• 作者: N. Cooper;A. Panteli;N. Shah

Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcohol

• DOI: 10.1039/c6gc00623j
• 发表时间: 2016-01-01
• 期刊: GREEN CHEMISTRY
• 影响因子: 9.8
• 作者: Bai, Yinjuan;De Bruyn, Mario;North, Michael
• 通讯作者: North, Michael

Wholly biomass derivable sustainable polymers by ring-opening metathesis polymerisation of monomers obtained from furfuryl alcohol and itaconic anhydride

• DOI: 10.1039/c7py00486a
• 发表时间: 2017-05
• 期刊: Polymer Chemistry
• 影响因子: 4.6
• 作者: Yinjuan Bai;J. Clark;T. Farmer;Ian D. V. Ingram;M. North

Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst

• DOI: 10.1021/acs.macromol.8b01224
• 发表时间: 2018-07-24
• 期刊: MACROMOLECULES
• 影响因子: 5.5
• 作者: Chen, Thomas T. D.;Zhu, Yunqing;Williams, Charlotte K.
• 通讯作者: Williams, Charlotte K.