Post-Combustion Carbon Capture Using MOFs: Materials and Process Development

该提案旨在根据FENCO-NET的主题4：新的创新二氧化碳捕获技术，制定一个国际合作研究计划。提案中涉及的具体问题是：1。1 .基于金属有机框架（MOF）材料的CO2捕集新工艺的综合评价；2 .合成（按比例放大到公斤数量），表征，制定和评估用于真空摆动（VSA）燃烧后捕获的选定mof；3 .研究和解决吸附剂在燃烧后碳捕获过程中的稳定性和效率问题；研究和模拟质量和传热动力学，以便在能源效率、运营和资本成本方面优化碳捕集装置所需的准确动态过程模拟。FENCO-NET呼吁为协调伙伴机构的重要研究工作提供了独特的机会。SINTEF有能力制备先进的mof，也可以按比例生产用于实验规模工艺测试的成形材料。UoE开发了新的快速筛选技术，特别是燃烧后的碳捕获，与SINTEF的密切合作将加速进一步的开发，并为指导新材料的合成提供必要的稳定性数据。只有将材料和工艺发展结合起来，才能在这一领域取得重大进展。CERTH在真空摆动吸附（VSA）建模、仿真、设计和优化方面具有重要的专业知识，UoE和SINTEF都有能力评估发电厂新型碳捕获系统的集成。

The proposal aims to develop an international collaborative research programme under Topic 4 of the FENCO-NET call: New innovative CO2capture technologies. The specific issues addressed in the proposal are:1. Overall evaluation of new innovative CO2 capture processes based on Metal Organic Framework (MOF) materials;2. To synthesise (scale-up to kg quantities), characterise,, formulate and evaluate selected MOFs for vacuum swing (VSA) post-combustion capture;3. To investigate and address adsorbent stability and efficiency in post-combustion carbon capture processes;4. To investigate and model mass and heat transfer kinetics to enable accurate dynamic process simulations needed for the optimization of thecarbon capture units with respect to energy efficiency and operational and capital costs.The FENCO-NET call gives the unique opportunity of coordinating the significant research efforts in the partner institutions. SINTEF has thecapability of preparing advanced MOFs which can also be scaled-up to produce formed materials for bench scale process testing. The UoE hasdeveloped new rapid screening techniques, specifically for post-combustion carbon capture and the close collaboration with SINTEF will acceleratefurther developments and provide essential stability data to direct novel material synthesis. Significant advances in this field can only be achieved ifmaterial and process development are combined. CERTH brings significant expertise in Vacuum Swing Adsorption (VSA) modelling, simulation, designand optimization and both the UoE and SINTEF have the capability of evaluating the integration of the novel carbon capture systems in power plants.