Nanocrystalline Photodiodes: Novel Devices for Water Splitting

纳米晶光电二极管：新型水分解装置

• 批准号: EP/F056230/1
• 负责人: Andrew Mills
• 金额: $ 66.09万
• 依托单位: University of Strathclyde
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2008
• 资助国家: 英国
• 起止时间: 2008 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FF056230%2F1
• 关键词: Nanocrystalline; Photodiodes; Novel; Devices; Water

The fossil fuel reserves of the world are rapidly diminishing and are also the prime cause for global warming. Solar energy represents a major, largely untapped energy source which could easily satisfy current and future global energy demands. Any solar energy conversion device must be inexpensive per m2, efficient and long-lasting. In this programme, novel, inorganic water-splitting systems, called macro-photocatalytic diode cells, MPCDs, utilising a range of new and established visible-light absorbing photocatalyst materials, will be developed for splitting water using sunlight in separate compartments. The latter feature is important as it will minimise, if not eliminate, the various efficiency-lowering recombination reactions associated with mixed product generation. The work programme involves a number of novel aspects including: the preparation of new nanoparticulate, crystalline photocatalyst materials, fabricating them into different novel photodiode formats and the synthesis and utilisation of new redox catalysts. The use of nanoparticulate semiconductor photocatalysts, made via continuous hydrothermal flow synthesis, CHFS, in conjunction with gel casting for robust porous supports, is a particularly important and novel advance, as too is the proposed combinatorial approach to the preparation of photocatalyst films by CVD. The project will develop a significant amount of the underpinning science required for the fabrication of the final, optimised, efficient MPCDs and include a study of the underlying reaction mechanisms, using time-resolved transient absorption spectroscopy. The proposal offers a route to achieving a step change in efficiency for energy capture from the sun and aims to deliver efficient, scalable demonstrators of the MPCD technology, suitable for development into pilot plant systems in the second phase of funding.

世界化石燃料储量正在迅速减少，也是全球变暖的主要原因。太阳能是一种主要的、基本上未开发的能源，可以很容易地满足当前和未来的全球能源需求。任何太阳能转换装置必须每平方米便宜，高效和持久。在该计划中，将开发新型无机水分解系统，称为宏观光催化二极管电池，MPCD，利用一系列新的和成熟的可见光吸收光催化剂材料，用于在单独的隔间中使用阳光分解水。后一个特征是重要的，因为它将最小化（如果不是消除的话）与混合产物产生相关的各种效率降低的重组反应。该工作计划涉及许多新的方面，包括：制备新的纳米颗粒，晶体光催化剂材料，将其制成不同的新型光电二极管格式，以及合成和利用新的氧化还原催化剂。使用纳米颗粒半导体光催化剂，通过连续水热流合成，CHFS，结合凝胶浇铸坚固的多孔支持，是一个特别重要的和新颖的进步，因为也是提出的组合方法，通过CVD制备光催化剂薄膜。该项目将开发制造最终，优化，高效的MPCD所需的大量基础科学，并包括使用时间分辨瞬态吸收光谱研究潜在的反应机制。该提案提供了一条实现太阳能捕获效率阶跃变化的途径，旨在提供高效、可扩展的MPCD技术示范，适用于在第二阶段融资中开发成试点工厂系统。

项目成果

Flagging up sunburn: a printable, multicomponent, UV-indicator that warns of the approach of erythema.

• DOI: 10.1039/b900569b
• 发表时间: 2009-03
• 期刊: Chemical communications
• 影响因子: 4.9
• 作者: A. Mills;Kate McDiarmid;Michael McFarlane;Pauline Grosshans