Parallel syntheis reactor

平行合成反应器

• 批准号: 346007-2007
• 负责人: Reaney, Martin
• 金额: $ 3.93万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Research Tools and Instruments - Category 1 (<$150,000)
• 财政年份: 2006
• 资助国家: 加拿大
• 起止时间: 2006-01-01 至 2007-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=325668
• 关键词: Parallel; syntheis; reactor

Synthetic organic chemistry yields routes to change the properties of plant oils and many are well known. Unfortunately, few of the processes are sufficiently economically feasible for use by industry. It is necessary therefore, to reduce these processes to practice in order to produce a wide variety of value-added consumer and industrial products. The equipment defined in this proposal is designed to screen for efficient industrial processes for converting vegetable oils to improved consumer and industrial products. The vegetable oils used in novel syntheses will be derived from Canadian crops having a unique chemistry and/or low cost ,including; canola, flax, high-oleic canola, solin flax, coriander, camelina and rapeseed. The equipment provides the ability to engage in parallel synthetic approaches which can greatly accelerate development of useful reactions to produce new products.   Modified oils will be synthesized through a series of reactions under well controlled conditions. Processes will be developed to inexpensively convert vegetable oils to products that: 1) remain liquid at low temperature (-40C); 2) have low viscosity (<4 cP); 3) have high viscosity (>200 cP); 4) have high polarity; 5) have low polarity; 6) have enhanced oxidative stability (>10 h AOM) 7) are more readily polymerized.   Patented methods and trade secrets have been developed by the applicant to prepare alkyl esters and conjugate fatty acids for industrial applications. The equipment will be used in training M.Sc. and Ph.D. candidates, as well as technicians and Postdoctoral Fellows, to conduct oil modification chemistry and to explore a wide range of reactions to modify the relevant properties of the lipids.

合成有机化学提供了改变植物油特性的途径，并且许多途径是众所周知的。不幸的是，很少有工艺在经济上足以供工业使用。因此，有必要减少这些流程的实施，以生产各种增值消费品和工业产品。该提案中定义的设备旨在筛选有效的工业流程，将植物油转化为改进的消费品和工业产品。新型合成中使用的植物油将源自具有独特化学性质和/或低成本的加拿大作物，包括：油菜籽、亚麻、高油酸油菜籽、索林亚麻、香菜、亚麻荠和油菜籽。该设备提供了采用并行合成方法的能力，可以极大地加速有用反应的开发以生产新产品。   改性油将在良好控制的条件下通过一系列反应合成。将开发以低成本将植物油转化为以下产品的工艺：1）在低温（-40℃）下保持液态； 2）具有低粘度（<4 cP）； 3）具有高粘度（>200 cP）； 4）具有高极性； 5）具有低极性； 6) 具有增强的氧化稳定性 (>10 h AOM) 7) 更容易聚合。   申请人已开发出专利方法和商业秘密来制备用于工业应用的烷基酯和共轭脂肪酸。该设备将用于硕士培训。和博士学位。候选人以及技术人员和博士后研究员进行油改性化学并探索各种反应以改变脂质的相关特性。