CO2 reforming of hydrocarbon gases

碳氢化合物气体的 CO2 重整

• 批准号: 262001-2007
• 负责人: Wang, Hui
• 金额: $ 1.6万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2009
• 资助国家: 加拿大
• 起止时间: 2009-01-01 至 2010-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=426901
• 关键词: CO2; reforming; hydrocarbon; gases

Carbon dioxide is the main component of greenhouse gases (GHG), of which the emission has climbed a historically-highest record and resulted in global warming and thus, more frequent extreme and damaging climate activities due to the massive exploitation and utilization of fossil fuels by human being. To ban this deleterious impact on our environment, one has been developing carbon dioxide sequestration technologies including geological storage, deep-sea storage and chemical conversion, in order to reduce and finally eliminate carbon dioxide emission to the atmosphere. Carbon dioxide reforming of methane and other light hydrocarbons, also known as dry reforming, converts carbon dioxide into synthesis gas from which a number of commodity chemicals and products are synthesized, forming one of the chemical utilization routes of carbon dioxide. However, the obstacle that prevents its commercialization is the lack of an industrially-satisfactory catalyst for dry reforming. To remove this obstacle, the strategy that Dr. Hui Wang at University of Saskatchewan uses is to first develop laboratory scale, highly active, ultra stable and well selective catalysts, to evaluate the acceptable catalyst under actual feedstock or simulated actual feedstock containing possible contaminants, to make industrial shaped catalyst, to study catalyst performance including mass transfer and heat transfer in larger scale, and to model the process for further scaling up. Thanks to the support from NSERC's Discovery grant, Dr. Wang and his students have successfully developed a composite catalyst that has undergone 2000 h life test and shown high activity and selectivity but no significant deactivation. Following this success, this project, also supported by NESERC's Dicovery grant, studies the catalyst performance in actual industrial feedstock, develops methods of industrial catalyst (pellet catalyst) preparation, evaluates the industrial catalyst, and models the process. In addition to the development of a commercial carbon dioxide conversion technology, the research work will provide opportunities of training high quality personnel in the areas of reaction engineering, catalyst development and GHG emission control for Canada.

二氧化碳是温室气体（GHG）的主要成分，其排放量已创历史最高纪录，人类对化石燃料的大量开采和利用导致全球气候变暖，极端破坏性气候活动更加频繁。为了消除这种对环境的有害影响，人们一直在开发二氧化碳封存技术，包括地质封存、深海封存和化学转化，以减少并最终消除二氧化碳排放到大气中。甲烷和其他轻烃的二氧化碳重整也称为干重整，将二氧化碳转化为合成气，合成气合成多种商品化学品和产品，形成二氧化碳的化学利用途径之一。然而，阻碍其商业化的障碍是缺乏工业上令人满意的干重整催化剂。为了克服这一障碍，萨斯喀彻温大学的Hui Wang博士采用的策略是首先开发实验室规模的高活性、超稳定和选择性好的催化剂，在实际原料或含有可能污染物的模拟实际原料下评估可接受的催化剂，制作工业成型催化剂，研究更大规模的催化剂性能，包括传质和传热，并为进一步放大的过程进行建模。在NSERC发现基金的支持下，王博士和他的学生成功开发了一种复合催化剂，该催化剂经过2000小时的寿命测试，表现出很高的活性和选择性，但没有明显的失活。继这一成功之后，该项目也得到了 NESERC 的 Dicovery 拨款的支持，研究实际工业原料中的催化剂性能，开发工业催化剂（颗粒催化剂）制备方法，评估工业催化剂，并对过程进行建模。除了开发商业二氧化碳转化技术外，这项研究工作还将为加拿大提供反应工程、催化剂开发和温室气体排放控制领域培养高素质人才的机会。