Canada Research Chair in Green Chemistry

加拿大绿色化学研究主席

• 批准号: CRC-2017-00056
• 负责人: Li, ChaoJun
• 金额: $ 14.57万
• 依托单位: McGill University
• 依托单位国家: 加拿大
• 项目类别: Canada Research Chairs
• 财政年份: 2020
• 资助国家: 加拿大
• 起止时间: 2020-01-01 至 2021-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=695286
• 关键词: Canada; Research; Chair; Green; Chemistry

Green Chemistry provides a new approach to reconciling the economic and environmental issues associated with chemical manufacture and use. The focus of this Chair in Green Chemistry is the discovery of novel chemical reactions of high efficiency and high atom-economy. In particular, this research will involve: (i) direct coupling of C-H and C-OH bonds as equivalents of C-X (halogen) bonds for various synthesis, (ii) catalytic activation of small molecules (CO2, CH4, and N2) under mild conditions, (iii) solar-energy-harvesting and redox-photo-catalyst free photo-assisted novel transformations, and (iv) umpolung of carbonyl compounds as alkyl carbanions for various nucleophilic reactions.

绿色化学为协调与化学品制造和使用相关的经济和环境问题提供了一种新的方法。这位绿色化学教席的重点是发现高效率和高原子经济性的新化学反应。特别是，这项研究将涉及：(I)作为C-X(卤素)键的等价物的C-H和C-OH键的直接偶联用于各种合成；(Ii)在温和的条件下催化小分子(CO2、CH4和N2)的活化；(Iii)太阳能捕集和无光催化氧化还原的新型光辅助转化；以及(Iv)作为烷基碳负离子的羰基化合物的Upolung用于各种亲核反应。