Materials Design and Mechanism Understanding of Electrodes for Next-Generation Batteries

下一代电池电极的材料设计和机理理解

• 批准号: RGPIN-2017-04409
• 负责人: Liu, Jian
• 金额: $ 2.11万
• 依托单位: University of British Columbia
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2020
• 资助国家: 加拿大
• 起止时间: 2020-01-01 至 2021-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=711030
• 关键词: Materials; Design; Mechanism; Understanding; Electrodes

With increasing global efforts to adopting clean energy, developing sustainable energy storage systems has become a major challenge in order to bring electric vehicles on the road, and to integrate intermittent renewable energy resources into the grid. Although Li-ion batteries are dominant in the market, they have great limitations in the energy density and cost for future large-scale applications. Therefore, it is essential to develop alternative battery systems with higher energy density and lower cost. Long-term objectives of this research program are to identify and develop new meso/nano-scale materials for next-generation battery technologies, and to develop fundamental understandings on synthesis-structure-performance relationship in energy materials and their underlying mechanisms. In a short term, this research program will design novel materials and concepts to address the critical challenges in Li-S batteries and Na-ion batteries, and bring these battery technologies closer to practical applications. Li-S batteries are considered a promising technology for electric vehicles, due to their theoretical energy density five times higher than state-of-the-art Li-ion batteries and extremely low cost of sulfur. However, current Li-S batteries suffer from low efficiency and limited cycle life, due to an unfavorable phenomenon called polysulfide shuttle effect. This research proposes to develop a ternary hybrid cathode material which can prevent the formation of polysulfide and dramatically improve the performance of Li-S batteries. Na-ion batteries are a potential electrical energy storage system for stationary applications, owing to the large abundance and low cost of Na sources as well as high theoretical energy density. The development of Na-ion batteries is hindered by the limited choice of electrode materials that an enable reversible Na ion storage. This research will develop a new group of phosphorus-based alloys and an electrode/electrolyte interface control strategy to deliver high-capacity electrode materials for Na-ion batteries. This research program will not only develop new materials design strategies to enable next-generation battery technologies, but also contribute to the advancement of new knowledge in materials science, interface science, and electrochemistry. The success of the proposed research would accelerate the rapid deployment of sustainable energy storage technologies and address the energy crisis and environmental consequences as a result of fossil fuels. This research program is of great importance to Canada's energy and environmental sectors, as Canada is committed to the development of renewable energy and reduction of greenhouse gas emission. This will keep Canada's leading position in renewable energy research and commercialization in the worldwide, and increase public awareness and education of renewable energy.

随着全球越来越多地采用清洁能源，开发可持续能源存储系统已成为一项重大挑战，以使电动汽车上路，并将间歇性可再生能源整合到电网中。虽然锂离子电池在市场上占据主导地位，但它们在能量密度和成本上有很大的局限性，难以在未来大规模应用。因此，开发能量密度更高、成本更低的替代电池系统势在必行。该研究项目的长期目标是为下一代电池技术识别和开发新的中/纳米尺度材料，并对能源材料的合成-结构-性能关系及其潜在机制进行基本理解。在短期内，该研究项目将设计新颖的材料和概念，以解决锂- s电池和钠离子电池的关键挑战，并使这些电池技术更接近实际应用。