Novel Nitrile-Nitrile C-C Coupling by Group 4 Metallocenes to 1 Metalla-2,5-diaza-cyclopenta-2,4-dienes and its Potential in Synthesis

在该团队以前的研究成果的基础上，该项目研究了氰类化合物的新的化学计量和催化反应。我们将详细研究最新报道的1-金属-2，5-二氮杂环戊二烯-2，4-二烯的合成，以及所形成的新型化合物的合成潜力。这是为了防止其他众所周知的主要是双核产物的不同的丁腈-丁腈偶联反应，这不是本项目的目标。

On the basic of former results of the team the project deals novel stoichiometric and catalytic reactions of nitriles. The very recently described formation of mononuclear 1-metalla-2,5-diazacyclopenta-2,4-dienes via selective nitrile-nitrile C-C coupling by reactions of nitriles with Group 4 metallocenes will be investigated in detail as well as the synthetic potential of the formed new type of compounds. This is to prevent other well known mostly dinuclear products of diverse nitrile-nitrile coupling reactions which are not ta he goal of this project.