Analytische Theorie der statischen und dynamischen Eigenschaften von wässrigen Polyelektrolytlösungen, Polyelektrolyte komplexerer Architektur

拟议的研究在2000年至2002年期间开始涵盖的主题，聚电解质在贫溶剂接近表面和限制的几何形状。在此指导开始之前，必须确定关于聚电解质在良溶剂（水）中的本体性质的几个开放点。最后几点涉及聚两性电解质和聚合盐的静态和动态。冻结状态（spingglass类型）的存在问题尚未解决。之后，计划解决不良溶剂性质。这些涉及单链状态下的项链结构，不良溶剂中的网络（和微凝胶）及其产生的弹性特性，接近表面和受限的几何形状。网络的研究是由最近的讨论分子功能和响应凝胶。对靠近表面的碳链、它们的吸附行为、它们的二维性质和受限几何结构的研究将能够预测原子力显微镜（AFM）和吸附实验的结果。我们将在所有这些不同的情况下，以及研究的影响，反缩合，我们预计在某些情况下强烈的构象变化。

The proposed research in the period 2000 to 2002 begins to cover the topic of polyelectrolytes in poor solvent close to surfaces and in restricted geometry. Before this directions are started several open points concerning the bulk properties of polyelectrolytes in good solvent (water) have to be finalized. These final points concern the statics and dynamics of polyampholytes and polymeric salts. The question of the existence of frozen states (of spinglass types) has not been solved yet. After, it is planned to work out poor solvent properties. These concern necklace structures in their single chain state, networks (and microgels) in poor solvent and their resulting elastic properties, close to surfaces and in restricted geometry. The research on networks are guided by recent discussions molecular function and responsive gels. The work on polyelectrolyte chains close to surfaces, their adsorption behavior, their two dimensional properties and in restricted geometries will be able to predict results for atomic force microscopy (AFM) and adsorption experiments. We will in all these different situations study as well the effects of the counterion condensation, where we expect strong conformational changes under certain circumstances.